Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Dertli, Enes(114)
- Kaya, Yunus(48)
- Şahin, Engin(48)
- İspirli, Hümeyra(47)
- Özen, Soner(38)
- Şenay, Volkan(37)
- Pat, Suat(36)
- Kutlu, Naciye(32)
- Artar, Musa(31)
- Can, Zehra(31)
- Korkmaz, Şadan(31)
- Yilmaz, Mustafa Tahsin(31)
- Öner, Erdal(31)
- Bayram, Sinan(30)
- Cuce, Erdem(30)
- Ertugrul, Mehmet(29)
- Hasar, Ugur Cem(29)
- Ecem Bayram, Nesrin(28)
- Mercan, Emin(28)
- Ayata, Ümit(27)
- Bayraktar, Bülent(27)
- Çolak, Murat(23)
- Özdemir, Akın(23)
- Ayazoglu, Rabil(22)
- Cuce, Pinar Mert(22)
- Sert, Durmuş(22)
- Bayram, Ozkan(21)
- Kamiloğlu, Aybike(21)
- Dirican, Ebubekir(20)
- Kadakal, Mahir(20)
- Abdioglu, Murat(19)
- Birinci, Ahmet(19)
- Tozlu, Alperen(19)
- Gerçek, Yusuf Can(18)
- Taylan, Osman(18)
- Cinar, Mehmet(17)
- Gul, Volkan(16)
- Hasar, Ugur C.(16)
- Kadakal, Huriye(16)
- Kara, Yakup(16)
Yayınlar
- MakaleYalnız künye2013Scopus SJRQ2The infrared, Raman, NMR and UV spectra, ab initio calculations and spectral assignments of 2-amino-4-chloro-6-methoxypyrimidine
Cinar, Z.; Karabacak, M.; Cinar, M.; Kurt, M.; Chinna Babu, P.; Sundaraganesan, N.
(Graph Presented) The 2-amino-4-chloro-6-methoxypyrimidine abbreviated as ACMP have been investigated by both the experimental and theoretical methods; through this work we provide the essential fact about the structural and vibrational insights. The optimized molecular structure, atomic charges, vibrational frequencies and ultraviolet spectral interpretation of ACMP have been studied by performing DFT/B3LYP/6-311++G(df,pd) level of theory. The FT-IR, FT-Raman spectra were recorded in the region 4000-400 cm -1 and 4000-50 cm-1 respectively. The UV absorption spectrum of the compound that dissolved in ethanol and water solution were recorded in the range of 200-400 nm. The scaled wavenumbers are compared with the experimental values. The difference between the observed and scaled wavenumber values of most of the fundamentals is very small. Based on the UV spectrum and TD-DFT calculations, the electronic structure and the assignments of the absorption bands were carried out. The 1H, 13C and DEPT 135 nuclear magnetic resonance (NMR) chemical shifts of the molecule were calculated using with the Gauge Including Atomic Orbital (GIAO) method and compared with experimental results. Besides, molecular electrostatic potential (MEP), frontier molecular orbitals (FMO) analysis were investigated using theoretical calculations.
AtıfScopus11WoS10OpenAlex11
İncele - MakaleAçık Erişim2013Scopus SJRQ1Reference-plane invariant transmission-reflection method for measurement of constitutive parameters of liquid materials
Hasar, Ugur Cem; Barroso, Joaquim José; Kaya, Yunus; Ertugrul, Mehmet; Bute, Musa
We propose a new transmission-reflection method for measuring constitutive parameters of liquid samples inside an asymmetric measurement cell (a sample over a low-loss holder in vertical position inside an empty waveguide section). We derived reference-plane invariant expressions for constitutive parameters measurement of liquid samples from reference-plane dependent scattering parameters. In addition, we also applied a simple approach for unique determination of transformation factor and reference-plane distances. After, we also investigated how the performance of the proposed method could be improved by performing a differential uncertainty analysis. From this analysis, we found the following key results: (a) the accuracy of the proposed method could be enhanced for low-loss liquid samples by using thicker samples, and (b) the effect of constitutive parameters and the length of the (low-loss) sample holder on constitutive parameters measurements of liquid samples by the proposed method is a key parameter in increasing the accuracy of the measurements. Finally, we performed constitutive parameter measurements of distilled water and methanol to validate the proposed method and compared the proposed method with similar methods in the literature. From the measurements, we note that our method is especially useful for liquid sample measurements when the reference-plane transformation factors are not known a priori and/or if the measurements are carried out over a high frequency range.
AtıfScopus20WoS19OpenAlex22İncele - MakaleAçık Erişim2013Scopus SJRQ1Effect of ultrasonic treatment on reduction of Esherichia coli ATCC 25922 and egg quality parameters in experimentally contaminated hens' shell eggs
Sert, Durmus; Aygun, Ali; Torlak, Emrah; Mercan, Emin
Backround: In this study, hen eggs which were experimentally contaminated with Esherichia coli ATCC 25922 were used. Contaminated eggs were washed statically (S5 to S30; 0 kHz) and by ultrasonic waves (U5 to U30; 35 kHz) for given applications of time (5, 15 and 30 min), then the eggs were stored at 22°C for 14 days. Results: Depending on the time of ultrasonic application, a significant increase in egg shell strength (P < 0.01) was recorded. The highest value of the Haugh unit (67.93, 1 day) was observed on the eggs which were washed by ultrasonic waves. Yolk width values of ultrasonic washed eggs diminished. E. coli was completely removed by 30 min of ultrasonic application. During storage E. coli growth was not detected on the eggs which were washed by ultrasonic waves except the eggs in U5 group (2.04 log CFU eggshell-1) on the first day of storage. Conclusion: Depending on the time of ultrasonic application a significant increase in egg quality parameters (shell strength, albumen height, Haugh units, and yolk height) were observed. The application of ultrasound led to a significant reduction in E. coli numbers on egg shells.
AtıfScopus21WoS20OpenAlex21İncele - MakaleAçık Erişim2013Scopus SJRQ2New water mites of the family Hygrobatidae (Acari, Hydrachnidia) from Turkey
Esen, Yunus; Pešić, Vladimir; Erman, Orhan; Kaya, Yücel
In this study, the findings of three water mite species of the family Hygrobatidae collected from different streams in Turkey were evaluated. Hygrobates (s. str.) anatolicus Esen & Pešić, sp. n. is described as new for science. Hygrobates (Rivobates) diversiporus Sokolow, 1927 and Atractides (s. str.) nikooae Pešić, 2004, which were illustrated and thoroughly discussed, are new records for the Turkish fauna.
AtıfScopus9WoS6OpenAlex8İncele - MakaleAçık Erişim2013Scopus SJRQ4Analysis of amplitude and slope diffraction coefficients
Tabakcioglu, Mehmet Bariş; Cansiz, Ahmet
The diffraction mechanism is used for field prediction in both light and shadowed regions. Slope and amplitude diffraction coefficients are vital to predict the field strength at the receiver accurately. In this paper, amplitude and slope diffraction coefficients for one of the ray theoretical models, the slope uniform theory of diffraction with convex hull (S-UTD-CH) model, are analyzed. Moreover, diffraction coefficients are given for knife-edge and wedge structures.
- MakaleAçık Erişim2013Scopus SJRQ1Comparison of the effects of different types of tube inserts on two-phase flow instabilities
Omeroglu, Gokhan; Çomaklý, Omer; Karagoz, Sendogan; Karsli, Suleyman
Turbulence promoting inner elements such as rings, wings or winglets, twisted tapes, etc., is widely used in single- and two-phase flows. In this experimental work, the two-phase flow instabilities of forced convection boiling in a horizontal tube with ring- and twisted-tape-type inner elements inside are investigated. In order to analyze the two-phase flow of water, the experiments were conducted under a constant system pressure of 7.5 bar, and a constant heat input of 24 kW was applied to the outer surface of the circular test pipe with constant exit restriction. Three different inlet temperatures (Ti = 15, 25, and 35°C) were used to see the effect of inlet sub-cooling, and the mass flow rate was decreased from 110 to 20 g/s to obtain the characteristic curve. Two different pitch ratios for both the ring and twisted tape were evaluated in terms of stability. The results were evaluated in terms of appropriate variables for both the tube with insertions and the smooth tube. The analysis shows that the pressure drop increases with decreasing mass flow rate for all cases. The presence of the inner elements in the test pipe causes the boundaries of the oscillations to narrow in comparison with smooth tube. On the other hand, with the increase in the effective diameter of the test pipe the boundaries of the oscillations broaden. For each type of insertion, the increase of the pitch ratio makes the system less stable.
AtıfScopus4WoS3OpenAlex6İncele - EditoryalAçık Erişim2013Preface of the "2nd symposium on metaheuristic and numerical analysis / engineering applications"
Nigdeli, Sinan Melih; Bekdaş, Gebrail; Toklu, Yusuf Cengiz; Altan, Şemsi Burhanettin
- MakaleYalnız künye2013Scopus SJRQ2Determination of structural, spectrometric and nonlinear optical features of 2-(4-hydroxyphenylazo)benzoic acid by experimental techniques and quantum chemical calculations
Cinar, Mehmet; Yildiz, Nihat; Karabacak, Mehmet; Kurt, Mustafa
The optimized geometrical structure, vibrational and electronic transitions, chemical shifts and nonlinear optical properties of 2-(4-hydroxyphenylazo)benzoic acid (HABA) compound were presented in this study. The ground state geometrical structure and vibrational wavenumbers were carried out by using density functional (DFT/B3LYP) method with 6-311++G(d,p) basis set. The vibrational spectra of title compound were recorded in solid state with FT-IR and FT-Raman spectrometry in the range of 4000-400 cm-1 and 4000-10 cm-1; respectively. The fundamental assignments were done on the basis of the recorded spectra and total energy distribution (TED) of the vibrational modes. The 1H and 13C NMR spectra were recorded in deuterated DMSO solution, and gauge-invariant atomic orbitals (GIAOs) method was used to predict the isotropic chemical shifts. The UV-Vis absorption spectra of the compound were observed in the range of 200-800 nm in ethanol, methanol and water solvents. To investigate the nonlinear optical properties, the polarizability, anisotropy of polarizability and molecular first hyperpolarizability were computed. A detailed description of spectroscopic behaviors of compound was given based on the comparison of experimental measurements and theoretical computations.
AtıfScopus19WoS19OpenAlex19İncele - MakaleYalnız künye2013Scopus SJRQ3Purification and characterisation of laccase from lactarius volemus and its application in removal of phenolic compounds from fruit juice
Nadaroglu, Hayrunnisa; Tasgin, Esen
Laccases are multicopper oxidases (EC 1.10.3.2.), widely distributed in fungi, higher plants and bacteria. In this research, a laccase from Lactarius volemus (Russulaceae) was purified by 73.08 fold using precipitate of saturation (NH4)2SO4, DEAE-cellulose and Sephacryl S200. It was shown that purified enzyme was homogeneous in term of SDS-PAGE with molecular mass estimated of 30 kDa. The pH was optimal at 4.0, enzyme was stable at pH 3.0-5.0 and optimal temperature was at 50°C. Cu2+ and Fe2+ were activated to the purified laccase enzyme, and it was partially inhibited by 5 mM concentration of some metal salts and EDTA, urea, SDS, L-cysteine, dithioeritritol and β-mercaptoethanol. In addition, it was investigated whether the purified and characterized laccase enzyme would remove the phenolic compound of some fruit juices which are responsible for haze formation and browning during storage. Their application led to reduction of total phenolic compounds for apple, apricot, cherry and grape juice. As a result, the effect of these enzymatic treatments on total phenol content and clarity of the juice were evaluated using a central composite design. This laccase enzyme had potential application in food processing.
AtıfScopus18İncele - MakaleYalnız künye2013Scopus SJRQ3Application of carrier element free coprecipitation (CEFC) method for determination of Co(II), Cu(II) and Ni(II) ions in food and water samples
Serencam, Huseyin; Duran, Celal; Ozdes, Duygu; Bektas, Hakan
A simple and highly sensitive separation and preconcentration procedure, which has minimal impact on the environment, has been developed. The procedure is based on the carrier element free coprecipitation (CEFC) of Co(II), Cu(II), and Ni(II) ions by using 2-{4-[2-(1H-indol-3-yl)ethyl]-3-(4-methylbenzyl)-5-oxo- 4,5-dihydro-1H-1,2,4-triazol- 1-yl}-N'-(pyridin-2-yl methylidene)acetohydrazide (IMOTPA), as an organic coprecipitant. The levels of analyte ions were determined by flame atomic absorption spectrometry (FAAS). The detection limits for Co(II), Cu(II) and Ni(II) ions were found to be 0.40, 0.16 and 0.17 μg L-1, respectively, and the relative standard deviations for the analyte ions were lower than 3.0%. Spike tests and certified reference material analyses were performed to validate the method. The method was successfully applied for the determination of Co(II), Cu(II) and Ni(II) ions levels in sea and stream water as liquid samples and red pepper, black pepper, and peppermint as solid samples.
AtıfScopus10WoS10İncele - MakaleAçık Erişim2013Scopus SJRQ2Time-dependent effect of salicylic acid on alleviating cold damage in two barley cultivars differing in cold tolerance
Mutlu, Salih; Karadaǧoǧlu, Ömer; Atici, Ökkeş; Taşǧin, Esen; Nalbantoǧlu, Barbaros
The time-dependent effect of salicylic acid (SA) on alleviating cold damage in the Tokak (tolerant) and Akhisar (sensitive) varieties of barley (Hordeum vulgare) was investigated. Seedlings subjected to 0.0, 0.1, and 1 mM SA for 7 days were transferred to cold (7/5 °C) on days 7, 14, 21, and 28 for 3 days. It was found that 0.1 mM SA had a greater alleviating effect, decreasing the freezing injury in both varieties for at least 10 days after the application. Moreover, 0.1 mM SA had a greater effect on alleviation in Tokak by increasing the ice nucleation activity of apoplastic proteins extracted from the leaves. SA was effective for at least 24 days in decreasing the effect of freezing temperature by regulating apoplastic proteins in the leaves after the application. Furthermore, 0.1 and 1 mM SA had an alleviating effect by decreasing the lipid peroxidation level in both varieties for at least 24 days after the application. It can be seen that SA treatment can play a positive role in alleviating cold damage in barley. Therefore, it is suggested that results from SA treatments may contribute to research related to diminishing cold damage in agricultural applications.
AtıfScopus21WoS8OpenAlex23İncele - MakaleAçık Erişim2013Scopus SJRQ2Biosorption properties of Morus alba L. for Cd (II) ions removal from aqueous solutions
Serencam, Huseyin; Ozdes, Duygu; Duran, Celal; Tufekci, Mehmet
The abundantly available industrial waste product Morus alba L. pomace (MAP) is one of the cost-effective biosorbent for removal of metal ions from aqueous solutions. Hence, in the present study, we aimed to test the ability of MAP to remove Cd(II) ions through batch biosorption process. Firstly, MAP was characterized using several techniques, and then the influence of various experimental parameters such as initial pH of the aqueous solution, initial Cd(II) concentration, contact time, MAP concentration, and temperature were evaluated upon the biosorption process. It was found that the maximum uptake of Cd(II) ions occurred at initial pH 6.0 and optimum contact time was observed as 60 min. Cd(II) ions adsorption on MAP analyzed by the Langmuir and Freundlich isotherm models and the maximum monolayer biosorption capacity of MAP was found to be 21.69 mg g-1 by using the Langmuir isotherm model. The pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion models were employed to describe the biosorption kinetics. In order to investigate the thermodynamic properties of the biosorption process, the changes in the Gibbs free energy (â̂†G), enthalpy (â̂†H), and entropy (â̂†S) were also evaluated and it has been concluded that the process was feasible, spontaneous, and endothermic in the temperature range of 5-40 C.
AtıfScopus38WoS36OpenAlex46İncele - MakaleAçık Erişim2013Scopus SJRQ4Protective Role of Mentha longifolia L. ssp. longifolia against Aflatoxin B
Ceker, Selcuk; Agar, Guleray; Alpsoy, Lokman; Nardemir, Gokce; Kizil, Hamit Emre; Mete, Ebru
The aim of this study was to investigate the effects of essential oil of Mentha longifolia L. ssp. longifolia, used since ancient times for the treatment of many digestive tract diseases, on the genotoxicity and oxidative stress by a single dose of Aflatoxin B1 (5 μM) in the human lymphocyte culture. The total of the 12 identified components accounted for 97.69 % by Gas chromatography (GC). Major components of the oil were cis-piperitone epoxide (26.52 %), piperitenone oxide (26.40 %), pulegone (15.66 %) and piperitenone (13.57 %). According to the results obtained from GC-MS systems, monoterpenes consist of 89.19 % of the total oil approximately while sesquiterpenes were represented in small quantities in the oil. We studied the anti-genotoxic effects of essential oils of M. longifolia (MEO) by using sister chromatid exchange (SCE) and micronucleus (MN) test systems. Also, the anti-oxidative effects of MEO were evaluated by using superoxide dismutase (SOD), glutathione peroxidase (GPx) and malondialdehyde (MDA) assay. The SCE frequency and the number of MN were increased when treated with AFB1. Especially, MEO at 1.5 and 2.0 μl reduced SCE frequency and MN number in the human lymphocyte (p <0.05). In addition, AFB1 treatment significantly reduced the activity of SOD and GPx and elevated the level of MDA (p<0.05). MEOs treatment led to significant attenuation of AFB1-induced oxidative stress by normalization of the activities of SOD and GPx and the MDA (p < 0.05). These results suggest that MEOs could provide anti-oxidative and anti-genotoxic protection for the oxidative and genotoxic agents that cause many diseases including cancer and neurodegenerative disease.
AtıfScopus10WoS11OpenAlex11İncele - MakaleAçık Erişim2013Scopus SJRQ1Spontaneous Mutation Reveals Influence of Exopolysaccharide on Lactobacillus johnsonii Surface Characteristics
Horn, Nikki; Wegmann, Udo; Dertli, Enes; Mulholland, Francis; Collins, Samuel R. A.; Waldron, Keith W.; Bongaerts, Roy J.; Mayer, Melinda J.; Narbad, Arjan
As a competitive exclusion agent, Lactobacillus johnsonii FI9785 has been shown to prevent the colonization of selected pathogenic bacteria from the chicken gastrointestinal tract. During growth of the bacterium a rare but consistent emergence of an altered phenotype was noted, generating smooth colonies in contrast to the wild type rough form. A smooth colony variant was isolated and two-dimensional gel analysis of both strains revealed a protein spot with different migration properties in the two phenotypes. The spot in both gels was identified as a putative tyrosine kinase (EpsC), associated with a predicted exopolysaccharide gene cluster. Sequencing of the epsC gene from the smooth mutant revealed a single substitution (G to A) in the coding strand, resulting in the amino acid change D88N in the corresponding gene product. A native plasmid of L. johnsonii was engineered to produce a novel vector for constitutive expression and this was used to demonstrate that expression of the wild type epsC gene in the smooth mutant produced a reversion to the rough colony phenotype. Both the mutant and epsC complemented strains had increased levels of exopolysaccharides compared to the wild type strain, indicating that the rough phenotype is not solely associated with the quantity of exopolysaccharide. Another gene in the cluster, epsE, that encoded a putative undecaprenyl-phosphate galactosephosphotransferase, was deleted in order to investigate its role in exopolysaccharide biosynthesis. The ΔepsE strain exhibited a large increase in cell aggregation and a reduction in exopolysaccharide content, while plasmid complementation of epsE restored the wild type phenotype. Flow cytometry showed that the wild type and derivative strains exhibited clear differences in their adhesive ability to HT29 monolayers in tissue culture, demonstrating an impact of EPS on surface properties and bacteria-host interactions.
AtıfScopus71WoS66OpenAlex72İncele - MakaleYalnız künye2013Scopus SJRQ3Bacteria-modified red mud for adsorption of cadmium ions from aqueous solutions
Kalkan, Ekrem; Nadaroglu, Hayrunnisa; Dikbaş, Neslihan; Taşgin, Esen; Çelebi, Neslihan
Cadmium is a toxic metal widely used in industry and it enters the environment from electroplating, smelting, alloy manufacturing, pigments, plastics, cadmium-nickel batteries, fertilizers, pesticides, mining, pigments and dyes, textile operations, and refining industries. Considering the harmful effects of cadmium, it is necessary to remove cadmium from liquid wastes at least to the limit accepted by regulations. The present study describes removal of cadmium from aqueous solutions using bacteria-modified red mud waste material. Batch adsorption experiments have been performed as a function of pH, contact time, temperature, and adsorbent dosage. The optimum results were obtained at pH 4.0, contact time of 60 min, temperature of 30°C, and an adsorbent dose of 1 mg/mL. The adsorption data was correlated with Langmuir and Freundlich adsorption models. The maximum adsorption capacity obtained from Langmuir adsorption model was 83.034 mg/g. The kinetic processes of cadmium adsorption on bacteria-modified red mud were described by applying pseudo-first-order and pseudo-second-order rate equations. The kinetic data for the adsorption process obeyed pseudo-second-order rate equations. Various thermodynamic parameters, such as ΔG°, ΔH°, and Δ15° were calculated and the negative value of ΔG° obtained indicate that the process was spontaneous, and the positive value of ΔH° confirms the reaction to be endothermic, and the positive value of ΔS° shows that the decrease in the degree of freedom of the adsorbed species. The bacteria-modified red mud investigated in this study exhibited a high potential for the removal of cadmium from aqueous solutions.
AtıfScopus30İncele - MakaleYalnız künye2013Scopus SJRQ2Molecular structure, electronic properties, NLO, NBO analysis and spectroscopic characterization of Gabapentin with experimental (FT-IR and FT-Raman) techniques and quantum chemical calculations
Sinha, Leena; Karabacak, Mehmet; Narayan, V.; Cinar, Mehmet; Prasad, Onkar
Gabapentin (GP), structurally related to the neurotransmitter GABA (gamma-aminobutyric acid), mimics the activity of GABA and is also widely used in neurology for the treatment of peripheral neuropathic pain. It exists in zwitterionic form in solid state. The present communication deals with the quantum chemical calculations of energies, geometrical structure and vibrational wavenumbers of GP using density functional (DFT/B3LYP) method with 6-311++G(d,p) basis set. In view of the fact that amino acids exist as zwitterions as well as in the neutral form depending on the environment (solvent, pH, etc.), molecular properties of both the zwitterionic and neutral form of GP have been analyzed. The fundamental vibrational wavenumbers as well as their intensities were calculated and compared with experimental FT-IR and FT-Raman spectra. The fundamental assignments were done on the basis of the total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanical (SQM) method. The electric dipole moment, polarizability and the first hyperpolarizability values of the GP have been calculated at the same level of theory and basis set. The nonlinear optical (NLO) behavior of zwitterionic and neutral form has been compared. Stability of the molecule arising from hyper-conjugative interactions and charge delocalization has been analyzed using natural bond orbital analysis. Ultraviolet-visible (UV-Vis) spectrum of the title molecule has also been calculated using TD-DFT method. The thermodynamic properties of both the zwitterionic and neutral form of GP at different temperatures have been calculated.
AtıfScopus53WoS53OpenAlex58İncele - MakaleAçık Erişim2013Scopus SJRQ2Energetic and exergetic comparison of air to air and air to water heat pumps according to evaporator conditions
Çomakli, Kemal; Çakir, Uǧur; Şahin, Erol; Kuş, Ayşegül Çokgez
This paper presents an experimental energetic and exergetic comparison for a heat pump system that can be run in different modes as air to air and air to water. Components of the heat pump do not change when the running mode changes, except for the condenser. This means that some external and internal effects (like compressor type, pipe lines) that can affect the system performance will be the same for each running mode. The comparison which was made in this study demonstrates which system leads to an efficient conversion and supply of energy and exergy. In the analysis, four balance (mass, energy, entropy and exergy) equations are applied to the system for the two modes. Exergy and energy efficiency values for both systems are given, while exergy destructions in each of the systems are determined and presented. It is seen that the heat pump unit which has the highest COP value is the air to air type (3.45-3.8); second is the air to water type (3.35-3.41). The exergy efficiency of the air to air heat pump (29-32%) is higher than the exergy efficiency of the air to water type heat pump (24.1-25). Ranking of the exergy destruction rates of the two heat pump types from high to low is as follows: air to air and air to water.
AtıfScopus5OpenAlex5İncele - MakaleAçık Erişim2013Scopus SJRQ2Application of S-UTD-CH model into multiple diffraction scenarios
Tabakcioglu, Mehmet Baris; Cansiz, Ahmet
Propagation prediction models based on ray tracing in coverage estimation for digital broadcasting systems are compared. Geometrical Theory of Diffraction (GTD), Slope Uniform Theory of Diffraction (S-UTD), and Slope UTD with Convex Hull (S-UTD-CH) models are compared for computation time and propagation path loss. S-UTD-CH model is optimum model with respect to computation time and relative path loss.
AtıfScopus8WoS7OpenAlex11İncele - MakaleYalnız künye2013Scopus SJRQ2Experimental and theoretical FTiR and FT-Raman spectroscopic analysis of 1-pyrenecarboxylic acid
Karabacak, M.; Cinar, M.; Kurt, M.; Chinna Babu, P.; Sundaraganesan, N.
The title molecule 1-pyrenecarboxylic acid (1PCA) has been characterized by FTiR, FT-Raman, NMR and UV-Vis spectral analyses. The molecular geometry, harmonic vibrational modes, the corresponding wavenumbers and iR intensities of 1PCA were calculated by DFT method with 6-311G(d, p) basis set. The assignments of the fundamentals were proposed on the basis of total energy distribution (TED) calculations. The calculated 13C and 1H NMR chemical shifts using gauge including atomic orbitals (GiAOs) approach are in good agreement with the observed chemical shifts. The polarizability and first order hyperpolarizability of the title molecule were calculated and interpreted. Using TD-DFT method, the electronic transitions have been compared with the experimental wavelengths. The molecular electrostatic potential map was used for prediction of possible hydrogen and oxygen bonding sites 1PCA molecule.
AtıfScopus45WoS43OpenAlex46İncele - MakaleYalnız künye2013Scopus SJRQ1Determination of aroma profiles of olive oils from Turkish olive cultivars
Bayrak, Ali; Kıralan, Mustafa; Kara, Hasan Hüseyin
This study analyzed volatile aromatic compounds present in the oils of Turkish olive cultivars. The cultivars Gemlik, AyvalIk, Memecik, Domat, Uslu, HalhalI, Kilis yaǧlIk, Nizip yaǧlIk, Haşebi and Karamani were harvested from important Turkish olive-growing locations, such as BalIkesir, Bursa, Manisa, AydIn, Muǧla, İzmir, Kilis, Mersin, Hatay and Gaziantep during the 2007-2008 and 2008-2009 growing seasons. Olive samples were collected in two harvest years, at almost the same maturity stage, and processed under the same conditions. Headspace solid-phase microextraction (HS-SPME) was used to analyze volatile aroma compounds in the olive oil samples. Forty-seven compounds were characterized and quantified using gas chromatography-mass spectrometry/flame ionization detector (GC-MS/FID). The most abundant identified compounds were trans-2-hexenal, hexanal and 3-methyl-1-butanol. The trans-2-hexenal, hexanal and 3-methyl-1-butanol contents of oil samples varied between 0.86-67.15, 3.93-61.82 and 0.48-84.74 %, respectively.
AtıfScopus11WoS11OpenAlex11İncele