Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2018Scopus SJRQ1
    Conjugated polythiophene/Ni doped ZnO hetero bilayer nanocomposite thin films: Its structural, optical and photoluminescence properties

    Bayram, Ozkan

    In this study, synthesis and characterization of plasma polymerized Thiophene/ Nickel doped Zinc Oxide (PTNZO) bilayer nanocomposite films were carried out. Nickel doped zinc oxide (NZO) thin films were obtained by magnetron sputtering technique on glass substrates at 40 W Radio Frequency (RF) power. Plasma polymerized Thiophene (PT) thin films were deposited on the NZO thin films obtained on the glass substrate by Radio Frequency (RF) plasma polymerisation technique. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), FTIR and Photoluminescence (PL) analyzes were performed for the characterization of PTNZO hetero bilayer nanocomposite films. In the XRD spectra of PTNZO bilayer nanocomposite thin films, (002) planes were determined as the most basic peak, and it was determined that the intensity of this peak, changed depending on the RF power of polymer thin films. Optical properties of nanocomposite thin films such as transmittance, absorbance and optical band gap were determined by UV–Vis spectroscopy. Optical band gap for PTNZO nanocomposites were 2.72 eV, 2.34 eV, and 2.45 eV, respectively, with increasing RF power. For NZO thin films, this value is 3.12 eV. The optical band gaps calculated from the absorption and transmittance spectra obtained using UV–visible spectroscopy had a good compatibility with those of the optical band spectra calculated from the PL spectra. The tetragonal wurtzite structure of the NZO thin films was examined by SEM analysis. The grain size of NZO nanostructure was found to be approximately 59 nm.

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  • MakaleYalnız künye2018Scopus SJRQ3
    Melissopalynological analysis for geographical marking of Kars honey; [Kars balının coğrafi İşaretlemesi İçin melissopalinolojik analiz]

    Çelemli, Ömür Gençay; Özenirler, Çiğdem; Bayram, Nesrin Ecem; Zare, Golshan; Sorkun, Kadriye

    In this research, the melissopalynological analysis of honey samples collected from Kars city located in the East Anatolian Region of Turkey was conducted for geographical marking. Within this context, melissopalynological analyses of 100 honey samples determined by sampling method were collected from eight districts of Kars in Eastern Anatolia Region of Turkey were done, to determine the nectarous source plants of Kars honey. As a result of melisopalynological analyses carried out in 100 honey samples; pollens of the taxa belonging to Apiaceae, Asteraceae, Berberidaceae, Betulaceae, Brassicaceae, Boraginaceae, Campanulaceae, Caryophyllaceae, Chenopodiaceae, Cistaceae, Cyperaceae, Dipsacaceae, Ericaceae, Fabaceae, Iridaceae, Lamiaceae, Liliaceae, Malvaceae, Onagraceae, Papaveraceae, Plantaginaceae, Poaceae, Polygonaceae, Ranunculaceae, Rhamnaceae, Rosaceae, Rubiaceae, Rutaceae, Salicaceae and Scrophulariaceae families were detected at different rates. Almost in all of the honey samples, Lotus corniculatus (in 99 samples), Onobrychis radiata (in 99 samples), Trifolium nigrescens (in 88 samples) from Fabaceae family and pollens of Echium vulgaris (81 samples) and Myosotis lithoospermifolia (15 samples) taxa from the Boraginaceae family, were found in honey samples. Onobrychis radiata pollen was the most intensely observed one among these samples (in dominant, secondary, minor, trace amounts). The total number of pollens (TPN-10) in 10 grams of honey were also detected during the melissopalynological analyses. TPN-10 values minimum: 226, maximum: 481157 and mean: 31678 were detected and the pollen abundance of the honeys are classified as good category. Kars is an important province for beekeeping with floral variety. As a result of this study, the first step of the geographical marking studies of Kars’ honey was completed.

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  • MakaleYalnız künye2018Scopus SJRQ1
    A new method for determination of dynamic stability of self-consolidating concrete: 3-Compartment sieve test

    Gökçe, H. Süleyman; Andiç-Çakır, Özge

    There are many standard test methods and applications to determine or estimate the workability of fresh concrete mixtures, most of them are focused on highly flowable concrete mixtures. Due to its high flowability, self-consolidating concrete (SCC) is much more vulnerable to segregation compared to conventional concrete mixtures. Thus, researchers have been working on adopting dynamic and static test methods for determination and improvement of segregation stability of those mixtures. In this study, the different segregation test methods presented in the literature were assessed and a novel method, i.e. 3-compartment sieve test, was introduced. The dynamic stability of fresh self-consolidating concrete mixtures was evaluated by the suggested test method after slump-flow and J-Ring tests. In conclusion, the developed new method is recommended for determination of segregation in SCC due to satisfactory concurrency of results with those of visual stability index test (0.67 ≤ R2 ≤ 0.90) and sieve segregation resistance test (0.83 ≤ R2 ≤ 0.90), respectively.

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  • MakaleYalnız künye2018Scopus SJRQ3
    Real-time implementation of self-tuning regulator control technique for coupled tank industrial process system

    Ayten, Kagan Koray; Dumlu, Ahmet; Kaleli, Aliriza

    This article presents the self-tuning regulator control technique for a coupled tank liquid level system that often used in industry. An autoregressive with exogenous model has been used as the liquid process model with the self-tuning control implementation in order to track the desired tank level trajectories with disturbances and uncertainties of the system dynamics. The designed self-tuning controller has been sensitive to parameter variations of the nonlinear coupled tank system. The parameters of the proposed controller are periodically updated themselves during the process by means of online recursive least square method with the forgetting factor algorithm. In this way, the parameter variations and unwanted disturbances of the system are eliminated in real-time application. In order to demonstrate the efficiency of the self-tuning regulator control technique, the real-time studies have been executed. The obtained experimental results demonstrated that the proposed controller gives the better trajectory tracking performance and smaller magnitude in overshot and undershot than the designed classical proportional–integral and sliding mode controllers.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
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  • MakaleYalnız künye2018Scopus SJRQ3
    Drug likeness scoring and quantitative structure anaplastic lymphoma kinase (ALK) inhibitors activities relationships of pyrazolone derivatives

    Ouadah, Karim; Tchouar, Noureddine; Belaidi, Salah; Oukil, Oualid; Cinar, Mehmet

    Series of twenty-four compounds was the field for applying multi-parameter optimization (MPO) methods and qualitative approximations of structural activity relationships in order to determine the role of various physico-chemical and quantum descriptors used in QSAR modeling as independent variables. Anaplastic lymphoma kinase (ALK) inhibitory activity was considered as a component in this study. In order to illustrate the quantitative relationships between the molecular descriptors and the activity of pyrazolone derivatives, we have applied a multiple linear regression (MLR) procedure. By adopting cross-validation with the leave-one-out method, we could estimate the predictability of models. Our results suggest a QSAR model based on the following descriptors: S, V, LogP, POL, Ref, HOMO, LUMO, E, , HBA, PSA and NRB, for the inhibitory activities against ALK. Results show high correlation between experimental and predicted activity values, indicating the validation and the good quality of the QSAR model.

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  • MakaleYalnız künye2018Scopus SJRQ2
    Influence of coronene addition on some superconducting properties of bulk MgB2

    Erdem, O.; Kirat, G.

    This study reports the effect of coronene (C24H12) addition on some superconducting properties such as critical temperature (Tc), critical current density (Jc), flux pinning force density (Fp), irreversibility field (Hirr), upper critical magnetic field (Hc2), and activation energy (U0), of bulk MgB2 superconductor by means of magnetisation and magnetoresistivity measurements. Disk-shaped polycrystalline MgB2 samples with varying C24H12 contents of 0, 2, 4, 6, 8, 10 wt%, were produced at 850 °C in Ar atmosphere. The obtained results show an increase in field-Jc values at 10 and 20 K resulting from the strengthened flux pinning, and a decrease in critical temperature (Tc) because of C substitution into MgB2 lattice, with increasing amount of C24H12 powder. The Hc2(0) and Hirr(0) values are respectively found as 144, 181, 172 kOe, and 128, 161, 145 kOe for pure, 4 wt% and 10 wt% C24H12 added samples. The U0 depending on the magnetic field curves were plotted using thermally activated flux flow model. The maximum U0 values are respectively obtained as 0.20, 0.23 and 0.12 eV at 30 kOe for pure, 4 wt% and 10 wt% C24H12 added samples. As a result, the superconducting properties of bulk MgB2 at high fields was improved using C24H12, active carbon source addition, because of the presence of uniformly dispersed C particles with nanometer order of magnitude, and acting as effective pinning centres in MgB2 structure.

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  • MakaleAçık Erişim2018Scopus SJRQ2
    Active control of a small-scalewind turbine blade containing magnetorheological fluid

    Bolat, Fevzi Cakmak; Sivrioglu, Selim

    This research study proposes a new active control structure to suppress vibrations of a small-scale wind turbine blade filled with magnetorheological (MR) fluid and actuated by an electromagnet. The aluminum blade structure is manufactured using the SH3055 (BergeyWindpower Co. Inc., Norman, OK, USA) code numbered airfoil which is designed for use on small wind turbines. A dynamic interaction model between the MR fluid and the electromagnetic actuator is constructed to obtain a force relation. A detailed characterization study is presented for the proposed actuator to understand the nonlinear behavior of the electromagnetic force. A norm based multi-objective H2/H∞ controller is designed using the model of the elastic blade element. The H2/H∞ controller is experimentally implemented under the impact and steady state aerodynamic load conditions. The results of experiments show that the MR fluid- electromagnetic actuator is effective for suppressing vibrations of the blade structure.

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  • MakaleYalnız künye2018Scopus SJRQ4
    Examination of main trends in geographical education research in Turkey

    Değirmenci, Yavuz

    The main purpose of the present study is to examine the main tendencies of the articles published in the field of geography education between the years of 2008 and 2018 in Turkey. Within the scope of this purpose, this study examined the subject fields, research methods, data collection tools, data analysis techniques and sampling methods used in the geography education studies in the journals scanned by the SSCI, ESCI and ULAKBIM social sciences databases in Turkey. The study used the document analysis method, one of the qualitative research methods. The study evaluated 224 articles determined according to the purposeful sampling method from the related databases by using the Geography Education Article Classification Form (GEACF) and then analyzed the obtained pieces of data by using the content analysis method and finally made some interpretations. According to the findings of the study, in the last ten years in Turkey, the highest number of articles were published in 2010 (n=33) and the lowest number of articles were published in 2017 (n=13). It was also observed that, in the field of geography education, the highest number of articles were published in the Marmara Geography Journal; however, in the journals scanned in SSCI, a total of (n=17) articles were published in the last ten years. Moreover, the studies were also determined to show more interest in the subject areas of teacher training and learning/teaching; questionnaires and scales were generally used as a data collection tool; the frequency/percentage and content analysis methods were preferred in the analysis of data; quantitative and qualitative methods were generally used in studies on geography education; on the contrary, mixed methods were less frequently used.

  • MakaleYalnız künye2018Scopus SJRQ2
    Optimum weight design of steel space frames with semi-rigid connections using harmony search and genetic algorithms

    Artar, Musa; Daloğlu, Ayşe T.

    In this paper, an optimization process using MATLAB-SAP2000 Open Application Programming Interface (OAPI) is presented for optimum design of space frames with semi-rigid connections. A specified list including W-profiles taken from American Institute of Steel Construction (AISC) is used in the selection of suitable sections. The stress constraints as indicated in load and resistance factor design of AISC, lateral displacement constraints being the top- and inter-storey drift and geometric constraints are considered in the optimization process. Genetic algorithm method based on biological principles and harmony search algorithm method based on the processes of musical harmony are used for optimum designs. Two different space frames are solved for the cases of rigid and semi-rigid connections, separately. A computer program is coded in MATLAB for the purpose interacting with SAP2000 OAPI. Results obtained from the analyses show that type of semi-rigid connections plays a crucial role in the optimization of steel space frames and increases the optimum weight.

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  • MakaleAçık Erişim2018Scopus SJRQ3
    Effects of choral, repeated and assisted reading strategies on reading and reading comprehension skills of poor readers

    Kodan, Hülya; Akyol, Hayati

    The main objective of this study was to explain the effects of choral, repeated and assisted reading strategies on fluent reading and reading comprehension skills of poor readers. The research was conducted with the single-subject research method and the multiple-subject model. The study group was consisted of six students who experience reading difficulties. The study was carried out in 90 hours. In the preliminary test, fluent reading and reading comprehension levels and reading mistakes of the students were determined. In this test, fluent reading level was lower than%89 and reading comprehension level was lower % 70, which showed that the students were at the Anxiety Level in both levels. During the study, choral, repeated and assisted reading strategies together had contributed to developments of the students’ fluent reading and reading comprehension skills both in the informative and the narrative texts. The data obtained during the research were analyzed by the Wilcoxon Signed-Rank Test. When examining the pre- and post assessment results, it was found that there was a significant difference between the word recognition percentages, number of incorrect words, number of words per minute, and the reading comprehension percentages in the informative text. In addition, it was articulated that there was a significant difference between the word recognition percentages, number of incorrect words, and the reading comprehension percentages in the narrative text. However, it was not found a significant difference between the numbers of words per minute in the narrative text. The data obtained at the end of the study shows that choral, repeated and assisted reading strategies have positive effects on the fluent reading and reading comprehension skills of the poor readers.

    • SDG 4 · Nitelikli Eğitim
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  • MakaleAçık Erişim2018Scopus SJRQ3
    Effects of Root Plant Growth Promoting Rhizobacteria Inoculations on the Growth and Nutrient Content of Grapevine

    Erdogan, Ummugulsum; Turan, Metin; Ates, Fadime; Kotan, Recep; Çakmakçi, Ramazan; Erdogan, Yasar; Kitir, Nurgül; Tüfenkçi, Sefik

    The objective of this study was to evaluate the effects of seven nitrogen (N2)-fixing and/or phosphorus (P)-solubilizing and siderophore-producing microorganism based bio-fertilizers in single and triple strain combinations isolated from the acidic rhizospheric soil of native tea, grapevine, and wild red raspberries. As a result of this study, bacterial efficiency was found to be variable and depended on the bacterial strains and evaluated growth parameters. Plant growth-promoting rhizobacteria (PGPR) has improved macro- and micro-nutrient concentrations in grapevine leaves, and stimulated plant growth. Triple inoculation and single inoculation based bio fertilizers were found to stimulate overall plant growth, including shoot and leaf weight, main shoot length, leaf ground index, chlorophyll, nitrogen, zinc and iron content of grapevine cv ‘Italy’. Bio-fertilizers increased the nutrients such as nitrogen, zinc and iron concentrations and consequently increased the chlorophyll content of the leaves.

    • SDG 2 · Açlığa Son
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  • MakaleYalnız künye2018Scopus SJRQ3
    Effect of cold-press carrot seed oil on the performance, carcass characteristics, and shelf life of broiler chickens

    Ürüşan, H.; Erhan, M.K.; Bölükbaşı, S.C.

    Present study aims to assess the effects of cold-press carrot seed oil (CSO) on performance, gut microflora, some serum biochemical parameters, meat color and meat shelf life of broiler chickens by experimenting with young broiler chicks. Accordingly, hundred fifty day-old Ross PM 308 broiler chicks were randomly given three different dietary treatments supplemented with 0 (control), 100mL/kg or 200 mL/kg (CSO). Five replicates of 10 birds each. It was observed that the supplementation of CSO led to an increase in weight gain, hot carcass and carcass yield on day 42. Addition of CSO supplement in the basal diet had no effect on serumbiochemical parameters. The number of lactic acid bacteria was higher in the group of chicks fed on the diet supplemented with 200 ml/kg CSO than in the other groups. Compared to the control group, dietary CSO supplement reduced the MDA values in leg muscles. L* (lightness) and b* (yellowness) values of the breast muscles increased in the chicks fed with 200 ml/kg CSO. Dietary 100 ml/kg CSO supplementation decreased a* (redness) values of the breast and leg muscles.In conclusion, supplementation of CSO had resulted in positive changes on weight gain,carcas yield, lactic acid bacteria count and breast tissue shelf life. As a result, this study suggests that cold-press carrot seed oil can be used as a dietary source of natural antioxidant for broilers.

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  • MakaleYalnız künye2018Scopus SJRQ4
    Future of fig production in Turkey

    Uzundumlu, Ahmet Semih; Oksuz, Muhammet Emre; Kurtoglu, Seval

    Fig is a fruit that grows in warm and humid climates; therefore, it is widely cultivated in the countries of Mediterranean climate zone. It has an important role in human nutrition with the minerals and Vitamins it contains. While fresh figs are offered for direct consumption, dried figs are used as the main or auxiliary ingredient in many desserts. Located in the Mediterranean climate zone, Turkey is an important fig producer and exporter with a share of 23% in world fig production. Although fig production is realized in 60 out of 81 provinces in Turkey, it is mostly produced in Aydin, Izmir, Bursa, Mersin, and Hatay provinces, which provide some 86 percent of the total production. The aim of this study is to predict the fig production trend of Turkey for the next 9 years from 2017 to 2025 using the fig production data from the period between 1991 and 2016 in order to enlighten the policy and decision makers regarding fig, an important export product of Turkey. The ARIMA model has been used to make the estimations in the study. According to the findings, it has been forecasted that Turkey’s fig production will decrease in the next ten years from 2017 to 2025 and the total share of five leading provinces will increase by 1 percent in fig production. It has also been estimated that fig production will increase in leading fresh fig producer provinces, whereas it will decrease in leading dried fig producer provinces in Turkey. It has been concluded that there is a need to create fresh fig demand in other countries for new exporting possibilities.

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  • MakaleAçık Erişim2018Scopus SJRQ3
    Optimum Design of Braced Steel Space Frames including Soil-Structure Interaction via Teaching-Learning-Based Optimization and Harmony Search Algorithms

    Daloglu, Ayse T.; Artar, Musa; Ozgan, Korhan; Karakas, Ali I.

    Optimum design of braced steel space frames including soil-structure interaction is studied by using harmony search (HS) and teaching-learning-based optimization (TLBO) algorithms. A three-parameter elastic foundation model is used to incorporate the soil-structure interaction effect. A 10-storey braced steel space frame example taken from literature is investigated according to four different bracing types for the cases with/without soil-structure interaction. X, V, Z, and eccentric V-shaped bracing types are considered in the study. Optimum solutions of examples are carried out by a computer program coded in MATLAB interacting with SAP2000-OAPI for two-way data exchange. The stress constraints according to AISC-ASD (American Institute of Steel Construction-Allowable Stress Design), maximum lateral displacement constraints, interstorey drift constraints, and beam-to-column connection constraints are taken into consideration in the optimum design process. The parameters of the foundation model are calculated depending on soil surface displacements by using an iterative approach. The results obtained in the study show that bracing types and soil-structure interaction play very important roles in the optimum design of steel space frames. Finally, the techniques used in the optimum design seem to be quite suitable for practical applications.

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  • MakaleAçık Erişim2018Scopus SJRQ2
    Effect of doping concentration on the structural and optical properties of nanostructured Cu-doped Mn3O4 films obtained by SILAR technique

    Bayram, Ozkan; Guney, Harun; Ertargin, Mehmet Emrah; Igman, Erdal; Simsek, Onder

    In this study, the effect of Cu doping on the optical, structural and wettability properties of the nanostructured Cu-doped Mn3O4 (CMO) thin films obtained by using successive ionic layer adsorption and reaction technique was systematically investigated. The optical, morphological, structural and wettability properties of the nanostructured CMO films were determined using scanning electron microscopy (SEM), X-ray diffraction (XRD), UV–Vis spectroscopy, and water contact angle (WCA) measurements. There were significant differences in the crystal structure of the nanostructured CMO thin films. The Cu doping disrupted this structure of pure (undoped) Mn3O4 films and caused the formation of the porous structure. Optical properties such as extinction coefficient, refractive index, and dielectric constants and optical band gap, were determined for nanostructured CMO films. Compared with pure films, the band gap of Cu-doped films decreased from 2.06 to 1.71 eV with increasing Cu concentration. The dielectric constants of the films showed that the nanostructured CMO films have a transparent structure. At 300 nm wavelength, the dielectric constants of pure Mn3O4 films were 2.22 while the calculated dielectric constants at increasing doping concentrations were 3.55, 2.41 and 2.25. It was also found from the WCA measurements that the thin films were hydrophilic in character and the WCA values for the nanostructured CMO thin films were measured as 24, 29 and 40 of degree.

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  • MakaleAçık Erişim2018Scopus SJRQ2
    Isolation and identification of exopolysaccharide producer lactic acid bacteria from Turkish yogurt

    İspirli, Hümeyra; Dertli, Enes

    Lactic acid bacteria (LAB) were isolated from traditional yogurt samples and genotypic characterization of these isolates revealed the presence of 21 distinct LAB strains belonging to Lactobacillus delbrueckii subsp. bulgaricus, Streptococcus thermophilus, Leuconostoc mesenteroides, and Lactobacillus plantarum as new LAB strains. Determination of the exopolysaccharide (EPS) production characteristics of the selected strains of each species revealed that all strains possessed at least one gene required for both homopolymeric- and heteropolymeric-type EPS production. Structural analysis of the EPSs showed that L. delbrueckii subsp. bulgaricus Y39 and S. thermophilus Y102 produced heteropolymeric EPS containing glucose and galactose, whereas Leuc. mesenteroides Y35 and L. plantarum Y36 produced homopolymeric glucan-type EPS. The level of EPS production in these strains was found to be in a similar range. These strains with EPS production characteristics are good candidates for future studies as new LAB for yogurt production. Practical applications: Recent trends in yogurt production technology have led to an increased use of ropy starter cultures in yogurt production due to the technological roles of exopolysacharides (EPS) produced by these cultures. The main role of EPS in yogurt production is to improve the textural properties of yogurt as an in situ produced natural polymer. In addition to the yogurt starter cultures, use of adjunct cultures during production of yogurt is also of special interest to enhance the technological and nutritional characteristics of yogurt. Therefore, in this study, potential yogurt starter and adjunct cultures from traditional yogurt samples with EPS production characteristics were isolated. From these isolates, Lactobacillus delbrueckii subsp. bulgaricus Y39 and Streptococcus thermophilus Y102 produced heteropolymeric EPS containing glucose and galactose, whereas Leuconostoc mesenteroides Y35 and Lactobacillus plantarum Y36 produced homopolymeric glucan.

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  • MakaleAçık Erişim2018Scopus SJRQ1
    Effect of high-pressure homogenisation on viscosity, particle size and microbiological characteristics of skim and whole milk concentrates

    Mercan, Emin; Sert, Durmuş; Akın, Nihat

    Effect of high-pressure (HPH) homogenisation on milk concentrates were studied. Skim and whole milk concentrates were homogenised at 0–150 and 0–40 MPa, respectively, and viscosity, particle size measurement, microbiological and colour characteristics determined. Up to a pressure of 120 MPa, viscosity of HPH-treated skim milk concentrates (SMC) was proportional to HPH pressure and was lower than that of the control (0 MPa). With whole milk concentrates (WMC), HPH decreased viscosity up to a pressure of 20 MPa; above 30 MPa viscosity increased. According to a power law model, both skim and whole milk concentrates showed shear-thinning flow behaviour. HPH at pressures above 120 MPa completely inactivated the microbial load of SMC. Up to a pressure of 50 MPa, HPH decreased the mean particle size (D [3,2]) of SMC; an increasing trend of D [3,2] was observed above 70 MPa. Except at 40 MPa, HPH decreased D [3,2] values of WMC samples.

    • SDG 2 · Açlığa Son
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  • MakaleYalnız künye2018Scopus SJRQ2
    Learning outcome literacy: The case of five elementary mathematics teachers

    Akdeniz, Dilsad Güven; Argün, Ziya

    Learning outcome (LO) literacy is conceptualized as a necessary skill for planning teaching and learning activities effectively. The skill has two main components: understanding and interpreting learning outcomes. The current study aimed to identify learning outcome literacy of elementary mathematics teachers with regard to this conceptualization. It is a case study based on the qualitative design. Participants were 5 mathematics teachers working at different elementary (5th - 8th grade) schools in Turkey. Observations and semi-structured interviews were used for data collection based on 10 learning outcomes selected from algebra and number learning domains in local mathematics curriculum. Content analysis method was used for data analysis. According to the findings, LO literacy can be regarded as a basic teacher competence and it requires the teacher to use the knowledge and skills he/she has. The results showed that participant teachers' LO literacy was insufficient. Considering the interrelation among its components, LO literacy should be developed with all the sub-components for effective teaching of LOs.

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  • MakaleAçık Erişim2018Scopus SJRQ2
    Development of cloud point extraction preconcentration of cadmium and lead in solid samples using flame atomic absorption spectrometry

    Bahadır, Zekeriyya; Yazar, Murat; Tümay, Süreyya Oğuz; Serencam, Hüseyin; Bektaş, Hakan; Duran, Celal

    2-[(6-Morpholin-4-ylpyridin-3-yl)amino]-N’-(4-oxo-3-phenyl-1,3thiazolidin-2-ylidene) acetohydrazide (MPAPTAH) was first used in a cloud point extraction procedure to determine the cadmium and lead ions in solid samples. Triton X-114 was used as a mixed micellar medium. The optimal extraction parameters (e.g. surfactant concentrations, amount of ligand, pH etc.) were evaluated. The optimum experimental conditions for Cd and Pb ions during the extraction procedure were carried out with 0.7 mg of MPAPTAH agent, 1.0 mL 0.2% (w/v) of the surfactant, a pH of 8.0. Under the best analytical parameters, the detection limit (LOD) for Cd(II) and Pb(II) ions were found to be 0.6 μg L−1 and 1.91 μg L−1, while the relative standard deviation (RSD) was taken as 2.78 and 2.86%, respectively. Preconcentration factor (PE) of 50 was obtained from using 50 mL of the sample volume for both ions. The accuracy of the method was tested through analysis of Pb2+ and Cd2+ in certified reference material (CRM Sandy Soil C). The interference effect of certain cations and anions were also investigated. The recoveries of the analyte ions were almost quantitative in the presence of all the interfering ions. Afterwards, the developed method was successfully applied to find lead and cadmium in real solid samples, including black tea, tobacco, and chili pepper.

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  • MakaleAçık Erişim2018Scopus SJRQ3
    Investigation of high-temperature-resistant rhenium–boron neutron shields by experimental studies and Monte Carlo simulations

    Korkut, Turgay; Korkut, Hatun; Aygün, Bünyamin; Bayram, Özkan; Karabulut, Abdulhalik

    In this study, novel rhenium–boron neutron-shielding high-temperature-resistant materials were designed. The considered samples, Re60–B40, Re58–B42, Re50–B50, and Re40–B60, with different concentrations of rhenium and boron were investigated to elucidate their neutron-shielding performances, and compare them with well-known neutron-shielding materials such as the 316LN quality nuclear steel. In addition to the experimental studies, Monte Carlo simulations were performed using the FLUKA and GEANT4 codes, where 4.5-MeV neutrons emitted by a 241Am–Be source were employed. Experimental equivalent dose rates, simulated track lengths, energy balances, and neutron mass absorption cross sections were discussed in detail.

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