Yayınlar
Koleksiyondaki öğeler
- MakaleAçık Erişim2023Scopus SJRQ2Determination of toxicity and radioprotective properties of bacterial and fungal eumelanin pigments
Bayram, Sinan; Aygün, Bünyamin; Karadayi, Mehmet; Alaylar, Burak; Güllüce, Medine; Karabulut, Abdulhalik
Purpose: Determination of the protective property of melanin, an organic polymer class consisting of phenolic and/or indolic compounds isolated from bacteria and fungi, against fast neutron radiation. To show that these melanin samples, which also have antioxidant and metal chelating properties, can be used as an active ingredient for a drug to be developed against neutrons used in nuclear research and medicine. Materials and methods: Bacterial and fungal media were prepared, and melanin pigments were produced and isolated. For molecular characterization of pigments, bacterial genomic DNA extraction, 16S rDNA gene amplification processes, and fungal genomic DNA extraction, ITS1, and ITS4 Gene Regions amplification were performed. The DEL assay was implemented to determine the genotoxicity properties of bacterial and fungal melanin pigments. Samples were prepared in a pad measuring 10 ml volume (60 × 15 mm) at a concentration of 0.2–1 microgram in 1% agarose gel for radiation-absorbed dose measurements. Absorption measurements were made using 241Am-Be fast neutron source and Canberra brand NP series BF3 gaseous detector to determine the neutron radiation absorption capacity of all samples. The results obtained to determine the absorption degrees of melanin samples were compared with paraffin and normal concrete, which are widely used in neutron radiation shielding studies. Results: Melanin pigments were obtained using different bacteria and fungi strains. Afterwards, the fast neutron radiation absorption capacity of these purified pigments were determined. Compared to reference samples, these pigments were found to have slightly lower radiation absorbing ability. In addition to these experiments, cytotoxicity tests were carried out using the Yeast DEL assay technique to evaluate the potential for use of these organic pigments in fields such as medicine and pharmacology. According to the results obtained from the tests, it was determined that these melanin samples did not have any toxic effects. Conclusion: It was determined that these melanin samples have the potential to be used as a radioprotective drug active substance to protect the tissues and cells of people exposed to neutron radiation after a nuclear accident or nuclear war. Giving a drug that will be developed by using these active ingredients before or after people are exposed to a radiation environment can provide great benefits.
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İncele - MakaleAçık Erişim2024Scopus SJRQ3Multifunctional electroless nickel boron composite coatings incorporated by magnesium diboride ceramic particles
Bülbül, Ferhat; Kara, Adem
In this study, the role of MgB2 in composite coatings is pivotal. Electroless Ni–B plating, a current-free chemical reduction process, deposits nickel–boron coatings. Other than MgB2, reinforcements like SiC, B4C, and so forth are used with Ni–B coatings for improved properties. The research focuses on Ni–B/MgB2 coatings on AISI 4140 steel using electroless deposition and annealing at different temperatures. Initially, the coating appears dense and amorphous, transforming into worm-like structures through crystallization with MgB2. Higher annealing temperatures lead to brush-like, feathery, and oyster mushroom structures, forming crystalline nickel boron compounds and oxide phases due to synergy. Interestingly, the newly introduced phases disrupt friction patterns nonlinearly, which is linked to MgB2’s ceramic nature and reinforcement quantity. Conversely, incorporating MgB2 and annealing-induced intermetallic phases notably enhances hardness (up to 6) and improves hydrophilicity and antibacterial traits in the coating.
AtıfScopus6WoS4OpenAlex4İncele - MakaleAçık Erişim2023Scopus SJRQ3Harmonic trigonometrically convexity
Kadakal, Huriye
In this study, we introduce and study the concept of harmonic trigonometrically convex functions and their some algebric properties. We prove two Hermite-Hadamard type inequalities for the newly introduced class of functions. We also obtain some refinements of the Hermite-Hadamard inequality for functions whose first derivative in absolute value, raised to a certain power which is greater than one, respectively at least one, is harmonic trigonometrically convex.
AtıfScopus10WoS12OpenAlex11İncele - MakaleAçık Erişim2024Scopus SJRQ2The Effect of Different Doses of Salt Stress on Germination and Emergence in Cannabis (Cannabis sativa L.) Seed Treated with Pre-Salicylic Acid
Gul, Volkan; Sefaoglu, Fırat; Cetinkaya, Hatice; Dinler, Burcu Seckin
It is known that salinity stress, one of the abiotic stress factors, significantly limits the germination, growth, development, and crop yield of plants. Therefore, this study was conducted to evaluate the effects of salinity (control, 50, 100 ve 150 mM) on seed germination and the effect of salicylic acid (control, 0.25, 0.50, 0.75 ve 1.00 mM) on seed germination to improve salt tolerance in cannabis seeds. The physiological characteristics of the plant, such as germination percentage, germination duration, germination index, radicle length, plumule length, wet radicle weight, dry radicle weight, wet plumule weight, and dry plumule weight, were analyzed. Depending on the salinity application dose, it was observed that there was a significant decrease in the germination parameters of cannabis seeds compared to the control. It was observed that salicylic acid treatments under salinity stress positively affected all the characters examined and reduced germination arrest due to increasing concentration levels. Although it is recommended to prepare seeds with 0.5 mM salicylic acid pre-application dose against salt stress of the cannabis plant,it is essential to expand the studies on its transfer to practice. As a result, salicylic acid will provide positive results that can be transferred to practice by increasing the resistance of cannabis plants against salinity, especially in agricultural soils with salt problems, as it will be more sensitive to pests and diseases.
AtıfScopus4WoS3OpenAlex3İncele - MakaleYalnız künye2024Scopus SJRQ1Effect of oxidation on radiation shielding capacity of ZrNbTaMoW Refractory High Entropy Alloys (RHEA) for nuclear reactor applications: Experimental and theoretical assessment
Sakar, E.; Guler, O.; Alim, B.; Guler, S.H.; Dikici, B.; Lampke, T.
This study presents the production and comprehensive assessment of a Refractory High Entropy Alloy (RHEA) with a ZrNbTaMoW composition for possible usage nuclear reactor applications. The alloy was synthesized using the mechanical alloying (MA) method, and its radiation properties were examined. Elemental powders of Zr, Nb, Ta, Mo, and W were utilized in equimolar quantities during the 120-hour MA process, conducted under a high-purity Ar atmosphere to prevent oxidation. The obtained HEA was then subjected to a mechano-thermal process to transform it into Refractory High-Entropy Oxide (RHEO) for comparing their radiation-shielding performance under oxide conditions. The characterization of the produced alloys through X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron dispersive spectroscopy (EDS). The photon shielding parameters of the alloys were experimentally obtained for various energies emitted from a 133Ba radioactive source, employing a Canberra UltraLEGe semiconductor detector. Furthermore, theoretical calculations were performed to validate the experimental data and to evaluate the alloys' photon shielding capabilities comprehensively. For this purpose, Phy-X/PSD software was employed to determine mass attenuation coefficients, half-value layer, effective atomic number, and effective electron density. Fast neutron absorption capabilities were determined through the calculation of average absorption cross-sections in the 2–12 MeV energy range. The results showed that the oxidation process significantly diminished the photon absorption capacity of RHEA.
AtıfScopus34WoS33OpenAlex37İncele - MakaleYalnız künye2023Scopus SJRQ2Effective Damping Coefficient of Fluid Viscous Dampers for Dynamic Response Mitigation of Coupled Frames
Düzgün, Oğuz Akın; Hatipoğlu, Yavuz Selim
Purpose: In this study, the effective damping coefficient of the fluid viscous dampers (FVDs) used for coupling two adjacent multi-story frames was investigated, considering soil-structure interaction (SSI) effects under seismic excitation. Methods: A numerical procedure was employed to obtain the dynamic response of the interconnected frames-soil system. The two-dimensional (2D) finite elements were used for the numerical treatment of the adjacent frames and soil region. Viscous boundary conditions were used as special non-reflecting boundaries on the edges of finite soil region. Five different damping coefficients of FVDs are considered to determine the effective damping coefficient. The effective damping coefficient of FVDs was determined by comparing the results from coupled frames with those of the uncoupled frames. Results: The results showed that the most affecting parameter on the system response was found to be soil type. It was also found that the sufficient damping coefficient of the viscous damper is equal to 1 × 105 N s/m for minimum response. Conclusion: When the effective damping coefficient of the FVDs was provided, the maximum values of the roof displacements, the roof accelerations, and the base shear forces are found to decrease by more than 40%.
AtıfScopus3WoS2OpenAlex4İncele - MakaleAçık Erişim2024Scopus SJRQ4Some Hermite-Hadamard type integral inequalities for functions whose first derivatives are trigonometrically ρ-convex
Kadakal, Huriye; Kadakal, Mahir
In this manuscript, we obtain refinements of the Hermite-Hadamard type inequalites for functions whose first derivative in absolute value, raised to a certain power which is greater than one, respectively at least one, is trigonometrically ρ-convex. We also show that our results coincide with previous results.
AtıfScopus3OpenAlex1İncele - Kitap BölümüYalnız künye2023Strategic brand management in enterprises: A conceptual review
Şaylan, Onur; Esmer, Yusuf
- MakaleYayıncıda açık erişim2024Scopus SJRQ1Enzyme Inhibitory, Physicochemical, and Phytochemical Properties and Botanical Sources of Honey, Bee Pollen, Bee Bread, and Propolis Obtained from the Same Apiary
Gercek, Yusuf Can; Dagsuyu, Eda; Basturk, Fatma Nur; Kırkıncı, Seran; Yıldırım, Nazlıcan; Kıskanç, Gamze; Özmener, Bahar; Unlu, Yigit Sabri; Kalkan, Seda Nur; Boztaş, Kadir
Bee products are an important source of nutrients and bioactive phytochemicals. This study aimed to determine the chemical composition (proximate composition, general phytochemical composition, sugar, and phenolic profiles) of four different products (honey, bee pollen, bee bread, and propolis), obtained from the same apiary, as well as to assess their biological activity through antioxidant and enzyme inhibition assays (α-amylase, α-glucosidase, lipase, AchE, neuraminidase, angiotensin-converting enzyme, urease, trypsin, tyrosinase, carbonic anhydrase, thioredoxin reductase, adenosine deaminase). Clear differences were observed among the samples in terms of both chemical composition and biological activity. The analysis revealed that bee pollen exhibited the highest carbohydrate content (87.9%), while propolis was identified as the richest source of phenolic compounds (14,858.9 mg/kg) among the analyzed samples. Propolis exhibited the highest biological activity in all applied antioxidant assays (CUPRAC, DPPH•, and ABTS•+) and in most enzyme inhibition assays. Notably, the α-glucosidase inhibition activity of propolis was comparable to that of the reference standard. In addition, honey exhibited remarkable trypsin inhibition, also comparable to the applied standard. These findings highlight the diverse bioactivities of hive products, which could play a key role in promoting health and preventing diseases.
AtıfScopus17WoS16OpenAlex16İncele - MakaleAçık Erişim2023Scopus SJRQ2Relationship between middle school students’ metacognition and problem-posing performance: A serial mediation analysis
Ada Yıldız, Kübra; Öztürk, Mesut
This study tests a model that predicts the problem-posing performance of sixth-grade students (independent variable metacognition, mediator variables mathematics and native language course success scores at the end of the year). The research was conducted with the relational model. The results regarding the mediation effect indicated that the mathematics course success scores and the native language course success scores were separately full mediators in the effect metacognition has on problem-posing performance. The results regarding serial mediation effect revealed that the mathematics course success scores and native language course success scores had a full mediating effect on the effect of metacognition on problem-posing performance.
AtıfScopus3OpenAlex2İncele - MakaleYalnız künye2023Scopus SJRQ2Development of the diabulimia knowledge level scale
Çetinkaya Özdemir, Serap; Semerci, Vahide; Sönmez Sarı, Ebru
The aim of this study was to develop the Diabulimia Knowledge Level Scale. The nurses voluntarily participated in the research (n = 384). The Diabulimia Knowledge Level Scale consists of 19 items and four factors. The four factors that make up the scale according to the results of Exploratory Factor Analysis explain 68.53 % of the total variance. The total Cronbach alpha coefficient of the scale was found to be 0.92. The Diabulimia Knowledge Level Scale is the first scale developed to determine the level of diabulimia knowledge among nurses. The scale is valid and reliable.
AtıfScopus2WoS2OpenAlex3İncele - MakaleAçık Erişim2024Scopus SJRQ2Investigation of Mass Transfer of Ozone in Jet Loop Reactor
Cengiz, Ibrahim; Değermenci, Nejdet; Yildiz, Ergun; Barlak, Melahat Semin
Mass transfer of ozone in a jet loop reactor was investigated in this study. Different parameters such as ozone gas concentration, gas flow rate, circulation flow rate, and spray nozzle diameter were examined for their effect on mass transfer. In experiments with ozone gas concentrations ranging from 3.83 to 17.1 g/m3, the KLa values remained unchanged, with an average of 28.7 ± 2.2 h−1. As the ozone gas concentration increased, the saturation values of ozone in the liquid phase also increased. Experiments were carried out with gas flow rates ranging from 50 to 250 L/h in the jet loop reactor, and increasing gas flow rates increased the KLa value up to five times. When the effect of the liquid circulation flow rate was examined for a spray nozzle diameter of 15.5 mm, increasing the flow rate from 40 L/min to 80 L/min increased the KLa value by approximately 41%. However, the power consumed per reactor volume for this process increased 8 times and reached 2.65 kW/m3. KLa values in the JLR vary between 6.1 and 37.3 h−1 depending on operating parameters and it has been concluded that it performs well compared to its counterparts.
AtıfScopus6WoS6OpenAlex7İncele - MakaleAçık Erişim2025Scopus SJRQ2THE EFFECTS OF THERMAL AGING ON COLOR AND GLOSSINESS IN UV CURED COATINGS APPLIED TO SESSILE OAK
Şahin, Sırrı; Ayata, Ümit; Esteves, Bruno
Color and glossiness are two important aesthetic properties of wood flooring and wood furniture that significantly affect consumers choice. With time the coating deteriorates altering the surface properties. Un-derstanding these changes is important for furniture industry, impacting design choices, material selection, and long-term maintenance. The effects of thermal aging (30 °C for 30 days, 60 °C for 60 days, and 90 °C for 90 days) on color parameters (C*, L*, b*. a*, ho) and glossiness on both perpendicular () and parallel (║) directions at 20°, 60°, and 85° angles in UV-cured coatings applied on sessile oak were studied. Results show that statistically significant differences were observed in the glossiness values, as well as in C*, b*, a*, L* and ho. As the temperature and duration of the thermal aging process increased, there was a noticeable increase in the values of color parameters b*, a*, and C*, while the values of ho and L* decreased. The characteristics of the surfaces exposed to thermal aging have undergone a complete transformation.
- MakaleAçık Erişim2024Scopus SJRQ2Antioxidant activity and phenolic composition of propolis from Marmara region, Turkey
Can, Zehra; Kara, Yakup; Kolayli, Sevgi; Çakmak, Ibrahim
This study investigated various properties of raw propolis samples from Marmara region of Turkey. Total phenolic content (TPF), total flavonoid (TFC) values, condensed tannin content (CTC) and phenolic profiles of ethanolic extracts (70%) were analyzed. Antioxidant activities were tested using the Ferric (III) reduction/antioxidant capacity (FRAP) and 2,2-Diphenyl-1-picrylhydrazyl (DPPH) radical scavenging methods. Phenolic profiles of the samples were analyzed using high performance liquid chromatography (RP-HPLC-UV) method. TPC, TFC and CTC values in the samples ranged from 52.9 to 203.5 mg GAE/g, 13.6 to 43.9 mg QUE/g, and 2.0 and 2.9 mg CTE/g, respectively. Caffeic acid phenyl ester (CAPE), chrysin, pinocembrin, rutin, and t-cinnamic acid were detected as the common phenolic components in all samples. In conclusion, Marmara region propolis is a rich source of bioactive compounds, especially flavonoids with antioxidant properties.
AtıfScopus14WoS12İncele - MakaleAçık Erişim2023Testing of waste vegetable oils as color modifiers in American walnut (Juglans nigra L.) wood; [Amerikan ceviz (Juglans nigra L.) odununda renk değiştirici olarak bitkisel atık yağların denenmesi]
Peker, Hüseyin; Esteves, Bruno; Ayata, Ümit
American walnut (Juglans nigra L.) wood is used for veneer due to its beautifully grained and dark-colored wood. This study was conducted to test the use of plant waste oils as color modifiers on American walnut wood. As waste vegetable oils, discarded walnut, olive, corn, and sunflower oils were employed. After applying waste oils to the wooden surfaces, several surface properties (brightness, color, and whiteness index: WI*) were determined. It was observed that multivariate analysis of variance tests conducted for WI* values and color parameters were found to be statistically significant. For all vegetable waste oils, decreases were identified in L*, C*, ho, and b* parameters, as well as in WI* values and glossiness values (for all degrees and orientations). The ∆E* values were measured at 19.18 for sunflower, 22.02 for walnut, 22.65 for corn, and 19.49 for olive. Each of the discarded vegetable oils had an impact on the color of the wooden surface. Keywords.
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İncele - MakaleAçık Erişim2024Scopus SJRQ1Efficient bioreduction of 4-phenyl-2-butanone to drug precursor (S)-4-phenyl-2-butanol by a whole-cell biocatalyst using a novel hybrid design technique
Bayhan, Beyzanur; Özdemir, Akın; Dertli, Enes; Şahin, Engin
Asymmetric synthesis is a critical tactic in pharmaceutical industries for creating chiral medications as it allows an enantiomer to be obtained in synthetic chemistry. The asymmetric bioreduction processes by biocatalysts have shown significant potential in producing chiral alcohols. The amount of substrate and the production method of the biocatalytic synthesis of (S)-4-phenyl-2-butanol ((S)-2) are not still desired levels. Furthermore, the biocatalytic asymmetric reduction of 4-phenyl-2-butanone (1) to (R)- or (S)-4-phenyl-2-butanol did not use any mathematical modeling techniques. In this study, the asymmetric bioreduction of 1 was carried out in this work employing Lactobacillus paracasei BD71 biocatalyst and a novel hybrid design-based optimization approach. By using the hybrid design technique, the optimal circumstances were discovered to be pH = 7, temperature = 29 °C, incubation period = 66 h, and agitation speed = 189 rpm. Also, the enantiomeric excess (ee) and conversion could be 99.15 % and 98.19 %, respectively. Next, (S)-2 was acquired to be ee: 99 %, conversion: >99 %, and yield: 97 % from the optimum bioreduction conditions. Furthermore, 14.08 g of 1 under optimal conditions was entirely transformed into (S)-2 (13.84 g, 97 % isolated yield). This study is the first research attempt to use a biocatalyst and an innovative and new hybrid design-based optimization approach to fabricate enantiopure (S)-2 at a high gram scale. This work has successfully demonstrated that the new hybrid design-based optimization technique is applicable to biocatalytic asymmetric reduction processes.
AtıfScopus9WoS8OpenAlex5İncele - MakaleAçık Erişim2023A New Approach on Some Special Curves
Aydın, Tuba Ağırman; Kocayiğit, Hüseyin; Kara, Meryem
In this paper, we obtain some characterizations for a Frenet curve with the help of an alternative frame different from the Frenet frame. Also, in the present study, we consider weak biharmonic and harmonic 1-type curves by using the mean curvature vector field of the curve. We also study 1-type and biharmonic curves whose mean curvature vector field is in the kernel of Laplacian. We give some theorems for such curves in the Euclidean 3-space. Moreover, we give the classifications of these types of curves.
- MakaleAçık Erişim2024Scopus SJRQ1Investigation of temperature effect on the optimal weight design of steel truss bridges using Cuckoo Search Algorithm
Keleş, Meryem; Artar, Musa; Ergün, Mustafa
In this article, the optimum weight design of steel truss bridges is carried out by considering the effect of temperature. One of the most significant issues such structures may encounter throughout their service life is the extreme temperature changes that can occur for various reasons. If a steel bridge is designed without considering this unfavorable scenario that might arise in the future, significant damage could happen in terms of the usability limit state, and it might even collapse by exceeding its carrying capacity before reaching its service life. Therefore, this study aims to conduct weight optimizations of steel truss bridges, considering the effect of temperature. Thus, it has been revealed how high-temperature variations alter material properties and affect the overall optimum weight of the structure. For this purpose, the minimum-weight designs of three planar steel truss bridges previously analyzed by other researchers have been re-evaluated using the Cuckoo Search Algorithm. The main program containing the flow steps of the algorithm based on the finite element method is coded in MATLAB. Stress and displacement limit values are used as constraints in solving the problems. The optimum weight results for each structure in the case of temperature effect not being considered are relatively similar. Thus, it has been demonstrated that the Cuckoo Search Algorithm can optimize such problems by comparing its results with similar studies in the literature. Then, the analyses are renewed by incorporating the temperature effect using this proven method. When the findings of both cases are examined, it is observed that the optimum weight values for all structures under the influence of temperature increase. This is due to the decrease in the material's modulus of elasticity because of the high-temperature change. In this case, the cross-section is insufficient owing to the loss of rigidity, and larger profiles are needed. The structure's weight tends to increase depending on the severity of the temperature. Also, numerical simulations of the structures under the same conditions are carried out with SAP2000 software to supplement the design optimization analyses detailed above and enrich the research content.
AtıfScopus16WoS13OpenAlex11İncele - MakaleAçık Erişim2024Scopus SJRQ2Mixed series solution for vibration and stability of porous bi-directional functionally graded beams
Turan, Muhittin
A new analytical solution based on the Ritz method is presented in this paper for analyzing the free vibration and buckling behavior of porous bi-directional functionally graded (2D-FG) beams under various boundary conditions. The solution is based on first-order shear deformation theory (FSDT). The selection of solution functions used in Ritz methods distinguishes the methods from each other and determines the accuracy of the analytical solution. To accurately capture the system's behavior and achieve the desired results, these functions have been carefully selected as a combination of polynomial and trigonometric expressions tailored as mixed series functions for each boundary condition. The study considers three types of porosity, namely PFG-1, PFG-2, and PFG-3. The equations of motion are derived using Lagrange's principle, taking into account the power-law variation of the beam material components throughout the volume. The non-dimensional fundamental frequencies and critical buckling loads are calculated for different boundary conditions, gradation exponents in the x and z directions (px, pz), slenderness (L/h), porosity coefficient (e), and porosity types. Initially, the accuracy of the mixed series functions is investigated for non-porous bi-directional functionally graded beams, and the numerical results are compared with existing literature to validate the proposed solution. Subsequently, the paper focuses on analyzing the influence of porosity on the free vibration and buckling behavior of bi-directional functionally graded beams using the developed solution method.
AtıfScopus21WoS22OpenAlex18İncele - MakaleAçık Erişim2023Scopus SJRQ2Morin ameliorates methotrexate-induced hepatotoxicity via targeting Nrf2/HO-1 and Bax/Bcl2/Caspase-3 signaling pathways
Kızıl, Hamit Emre; Caglayan, Cuneyt; Darendelioğlu, Ekrem; Ayna, Adnan; Gür, Cihan; Kandemir, Fatih Mehmet; Küçükler, Sefa
Background: Organ toxicity limits the therapeutic efficacy of methotrexate (MTX), an anti-metabolite therapeutic that is frequently used as an anti-cancer and immunosuppressive medicine. Hepatocellular toxicity is among the most severe side effects of long-term MTX use. The present study unveils new confirmations as regards the remedial effects of morin on MTX-induced hepatocellular injury through regulation of oxidative stress, apoptosis and MAPK signaling. Methods and results: Rats were subjected to oral treatment of morin (50 and 100 mg/kg body weight) for 10 days. Hepatotoxicity was induced by single intraperitoneal injection of MTX (20 mg/kg body weight) on the 5th day. MTX related hepatic injury was associated with increased MDA while decreased GSH levels, the activities of endogen antioxidants (glutathione peroxidase, superoxide dismutase and catalase) and mRNA levels of HO-1 and Nrf2 in the hepatic tissue. MTX treatment also resulted in apoptosis in the liver tissue via increasing mRNA transcript levels of Bax, caspase-3, Apaf-1 and downregulation of Bcl-2. Conversely, treatment with morin at different doses (50 and 100 mg/kg) considerably mitigated MTX-induced oxidative stress and apoptosis in the liver tissue. Morin also mitigated MTX-induced increases of ALT, ALP and AST levels, downregulated mRNA expressions of matrix metalloproteinases (MMP-2 and MMP-9), MAPK14 and MAPK15, JNK, Akt2 and FOXO1 genes. Conclusion: According to the findings of this study, morin may be a potential way to shield the liver tissue from the oxidative damage and apoptosis.
AtıfScopus74WoS71OpenAlex82İncele
