Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2024Decolorization of acid yellow 17 by ozonation and peroxone (O3/H2O2) process
Cengiz, Ibrahim
In this study, the decolorization of Acid Yellow 17, a mono azo dye with a wide range of applications such as in food, textiles, personal care products, and household cleaning products, was investigated in aqueous solutions using ozonation and peroxone processes. The effects of ozone gas flow rate (150, 200, and 250 L/h), ozone gas concentration (5.5, 11, and 16.5 g/m3), initial dye concentration (100, 200, and 300 mg/L), and hydrogen peroxide concentration (25, 50 and 62.5 mg/L) on decolorization in the batch bubble reactor were investigated. When the ozone gas flow rate was increased from 150 L/h to 200 L/h in the ozonation process, the removal efficiency increased from 70% to 80.2%. At gas flow rates above 200 L/h, removal was negatively affected. The removal efficiency increased with increasing ozone gas concentration, and at the end of the 45-minute reaction time, a removal efficiency of 98% was achieved at an ozone gas concentration of 16 g/m3. The increase in initial dye concentrations decreases the removal efficiency due to the increase in the amount of pollutant per unit ozone molecule. In the peroxane process, the effect of hydrogen peroxide on color removal was limited. It was determined that the ozonation process was more effective for the removal of Acid Yellow 17 from aqueous solutions.
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İncele - MakaleAçık Erişim2024Scopus SJRQ2Investigation of Mass Transfer of Ozone in Jet Loop Reactor
Cengiz, Ibrahim; Değermenci, Nejdet; Yildiz, Ergun; Barlak, Melahat Semin
Mass transfer of ozone in a jet loop reactor was investigated in this study. Different parameters such as ozone gas concentration, gas flow rate, circulation flow rate, and spray nozzle diameter were examined for their effect on mass transfer. In experiments with ozone gas concentrations ranging from 3.83 to 17.1 g/m3, the KLa values remained unchanged, with an average of 28.7 ± 2.2 h−1. As the ozone gas concentration increased, the saturation values of ozone in the liquid phase also increased. Experiments were carried out with gas flow rates ranging from 50 to 250 L/h in the jet loop reactor, and increasing gas flow rates increased the KLa value up to five times. When the effect of the liquid circulation flow rate was examined for a spray nozzle diameter of 15.5 mm, increasing the flow rate from 40 L/min to 80 L/min increased the KLa value by approximately 41%. However, the power consumed per reactor volume for this process increased 8 times and reached 2.65 kW/m3. KLa values in the JLR vary between 6.1 and 37.3 h−1 depending on operating parameters and it has been concluded that it performs well compared to its counterparts.
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İncele - MakaleYalnız künye2022Scopus SJRQ1High-speed treatment of low strength domestic wastewater for irrigation water production in pilot-scale classical, moving bed and fixed bed hybrid MBRs
Tuluk, Banu; Yildiz, Ergun; Nuhoglu, Alper; Tataroglu, Numan Suadi; Gulluce, Ekrem; Cengiz, Ibrahim; Degermenci, Nejdet; Angin, Ilker
To evaluate the treatability of domestic wastewater under conditions of low hydraulic retention time and high organic loadings, 3 pilot-scale automatically controlled membrane bioreactors (MBRs) as classical (C-MBR), moving bed (MB-MBR), and fixed bed (FB-MBR) were established and operated for a total of 268 days. Established pilot plants were compared in terms of treatment performance, membrane fouling, irrigation water criteria, and power consumption values. Results obtained have shown that all three systems were able to achieve more than 93% removal of chemical oxygen demand (COD) in an average hydraulic retention time (HRT) of 1 hour, and MB-MBR and FB-MBR were superior in terms of total nitrogen (TN) and total phosphorus (TP) removals. It has been determined that MB-MBR and FB-MBR are also advantageous in terms of power consumption. Especially it has been found that FB-MBR can produce better quality irrigation water with 40% lower power consumption than C-MBR under the same conditions. It was concluded that biofilm-supported hybrid systems could be a practical application in the fight against increasing water scarcity and global warming, both in obtaining clean water with less power consumption and in protecting human and environmental health.
AtıfScopus16WoS11OpenAlex17İncele - MakaleAçık Erişim2020Zeytin Karasuyunun İleri Oksidasyon Prosesleri İle Arıtımının İncelenmesi
Cengiz, Ibrahim; Kul, Sinan; Torun, Fatma Ekmekyapar
Bu çalışmada, Balıkesir ilinde faaliyet gösteren bir zeytinyağı üretim tesisinden temin edilen zeytin karasuyunun arıtımında ozon (O3), ozon+hidrojen peroksit (O3+H2O2) ve fenton (Fe2++H2O2) proseslerinin etkinlikleri incelenmiştir. İlk olarak %10 kapasite ile O3 jeneratörü çalıştırılmış ve 3 farklı pH (4.75, 10 ve 11) değerinde 6 saat boyunca ozonlama işlemi gerçekleştirilmiş ve maksimum giderim verimi pH değeri 11 olarak ayarlandığında %15.27 olarak hesaplanmıştır. İkinci olarak %10 kapasite ile O3 jeneratörü çalıştırılmış ve ortama 500 mg L-1 H2O2 ilave edilmiştir. 6 saatlik bu deneme sonrasında giderim verimi %9.8 olarak gerçekleşmiştir. Son olarak zeytin karasuyunun arıtımı için farklı Fe2+ (2.014 g L-1 ve 4.028 g L-1) ve H2O2 (19.05, 44.44 ve 80 g L-1) konsantrasyonlarının etkilerinin incelendiği fenton prosesinde Fe2+ ve H2O2 konsantrasyonları arttığında deney sonunda ortamda kalan KOİ konsantrasyonları sürekli azalmıştır. Fe2+ konsantrasyonu 4.029 mg L-1 ve H2O2 konsantrasyonu 80 mg L-1 olarak ayarlanmış ve %81.94 oranında KOİ giderimi sağlanmıştır. Elde edilen sonuçlar fenton prosesinin, diğer proseslerden çok daha fazla etkinliğinin olduğunu ortaya çıkarmıştır.
AtıfOpenAlex2İncele - MakaleYalnız künye2020Scopus SJRQ1Comparison of phenol removal with ozonation in jet loop reactor and bubble column
Barlak, Melahat Semin; Degermenci, Nejdet; Cengiz, Ibrahim; Ucun Özel, Handan; Yildiz, Ergun
This study aimed to remove phenol with ozonation in a jet loop reactor (JLR) and a bubble column (BC). In the first stage of the study, the mass transfer properties of JLR were determined and superiority over BC reactors were shown, and in the second stage, these reactors were used in phenol removal studies. At the same conditions, the volumetric mass transfer coefficient of JLR was 0.540 min-1, while this value was determined as 0.246 min-1 in the BC reactor. In phenol removal, the effects of initial phenol concentration, ozone dosage and pH on phenol and chemical oxygen demand (COD) removal were determined for both JLR and BC. While the pseudo-first rate constant for phenol removal in JLR at 221 mg/min ozone dosage was 0.1756 min-1, this value was only calculated as 0.1157 min-1 in the BC reactor. As a result, it has been shown that JLRs can achieve higher ozone gas transfer with lower energy consumption and perform more effective phenol and COD removal than BC reactors, especially at low pH and high ozone dosages.
AtıfScopus40WoS36OpenAlex39İncele