Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleYalnız künye2025Scopus SJRQ1Eco-friendly reduction of graphene oxide using urea: An optimized approach for high-performance rGO
Ucuncuoglu, Didar; Bektaş, Enes; Karakaş, İbrahim Hakkı; Amin Bhuiyan, Mohammad Ruhul; Korucu, Haluk
The growing demand for environmentally friendly and cost-effective approaches has accelerated the development of sustainable methods for the synthesis of reduced graphene oxide (rGO). In this study, urea was utilized as a green reducing agent for rGO synthesis, offering an alternative to conventional toxic chemicals. The synthesized rGO was comprehensively characterized using FTIR, SEM-EDS, Raman spectroscopy, XRD, BET analysis, zeta potential, and conductivity measurements. These analyses revealed key functional, structural, and morphological properties, including surface functional groups, elemental composition, carbon-to-oxygen (C/O) ratio, particle size (PS), crystallite size (CS), specific surface area (SSA), zeta potential (ZP), thermal conductivity (TC), and electrical conductivity (EC). Process optimization was performed using the Taguchi L4(23) orthogonal array design across nine quality parameters. Under optimal conditions, notable enhancements were achieved: C/O ratio increased by 108%, ID/IG ratio by 164%, I2D/IG ratio by 26%, CS by 75%, and SSA by 134%, while PS was reduced by 37%. Furthermore, ZP and TC increased by 58% and 33%, respectively, whereas EC was reduced by 97%. These findings demonstrate the potential of urea as a sustainable and effective reducing agent in the production of high-performance rGO materials.
AtıfScopus3WoS3OpenAlex3
İncele - MakaleAçık Erişim2025Scopus SJRQ2High-Performance Microwave-Absorbing Hemp Textile: Ni-Zn Ferrite and Multiwalled Carbon Nanotubes-Infused Nanocomposite for X-Band Electromagnetic Interference Shielding
Teber, Pembe; Teber, Ahmet; Karakaş, İbrahim Hakkı
This study aims to develop a flexible and sustainable electromagnetic (EM) wave-absorbing material by using hemp fabric as a substrate incorporated with multiwalled carbon nanotubes (MWCNTs) and magnetic Ni-Zn ferrite nanoparticles (NPs). In this context, the objective is to achieve effective EM attenuation across a wide frequency range using a green, lightweight composite to meet the rising demand for ecofriendly shielding in electronic and communication systems. Ni0.5Zn0.5Fe2O4 and MWCNT composite NPs are uniformly dispersed in a molten paraffin binder and impregnated into hemp fabrics. The magnetic NPs are synthesized via the microwave-assisted combustion method. The EM parameters of the resulting structure are determined in the X-band using experimental scattering data and the Nicholson–Ross–Weir method. Absorption performance is evaluated based on varying weight ratios of magnetic NPs and MWCNTs, with an emphasis on impedance matching. The results indicate that combining dielectric and magnetic components significantly enhances absorption. A maximum reflection loss of −72.42 dB and a 3.81 GHz bandwidth (covering over 90.71% of the X-band) are achieved at 10.08 GHz. Increasing Ni-Zn content shifts the resonance to higher frequencies. This sustainable, flexible composite shows strong potential for electromagnetic interference shielding, particularly in defense applications requiring radar invisibility.
AtıfScopus1WoS1OpenAlex1İncele - MakaleAçık Erişim2024Scopus SJRQ3InvestIgatIon of cytotoxIcIty and antIbacterIal effect of boron-contaInIng nano-hydroxyapatIte
Aydın, Numan; Karaoğlanoğlu, Serpil; Süloğlu, Aysun Kılıç; İdil, Neslihan; Demir, Merve; Karakaş, İbrahim Hakkı
Introduction: Different regenerative materials are used to protect and stimulate pulp tissue. Objectives: This in vitro study aimed to examine the cytotoxicity of different doses of boron-containing nano-hydroxyapatite (B-nHAp) and its antibacterial effect. Material and methods: B-nHAp was synthesized with microwave-assisted chemical precipitation method at different rates, such as 1%, 5%, and 10%. The extracts were prepared in separate tubes: 1%, 5%, 10% B-nHAp, and nHAp 50 mg/ml. Cytotoxicity test was performed on L929 mouse fibroblasts for 24 and 72 hours. Antibacterial analysis was performed with Streptococcus mutans bacteria using micro-dilution method. Cell viability values were evaluated with two-way analysis of variance (ANOVA) test (p < 0.05). Results: B-nHAp was successfully synthesized in XRD and SEM analyses. Nano-hydroxyapatite showed more cell viability than control group at 24 and 72 hours. All B-nHAp extracts demonstrated less cell viability at the end of 24 hrs. than control group. However, 1% B-nHAp cell viability decreased more in the B-nHAp group compared with the control group, while 5% and 10% B-nHAp showed high cell viability after 72 hours of incubation. B-nHAp demonstrated less antibacterial effect on Streptococcus mutans compared with nHAp. Conclusions: According to the results, the addition of boron to nano-hydroxyapatite does not make a significant contribution to increase the regenerative and antibacterial properties of the material.
AtıfScopus4OpenAlex5İncele - MakaleYalnız künye2022Scopus SJRQ2Photocatalytic activity of cobalt aluminate nanoparticles synthesized by microwave-assisted combustion method
Karakaş, İbrahim Hakkı; Karcıoğlu Karakaş, Zeynep; Ertuğrul, Mehmet
Cobalt aluminate is one of the most widely-used spinel aluminate types. It is known that various structural, magnetic and morphological properties of spinel ceramics can vary depending on the synthesis technique and the starting chemicals used. In this study, initially, heat treatment was applied to cobalt aluminate nanoparticles synthesized by the microwave-assisted combustion method and the effects of the applied heat treatment on the structural properties were investigated. Characterization studies showed that cobalt aluminate spinel pigments were successfully synthesized. The optimum heat treatment temperature was determined as 700 °C. Then, the synthesized cobalt aluminate nanoparticles were used as photocatalysts for dye removal by photocatalytic oxidation from a synthetic wastewater containing Astrazon red textile dye and their photocatalytic activity was investigated at different catalyst dosages. Moreover, the same particles were also produced by conventional combustion technique. Then, their photocatalytic activities were studied and the data were compared with the results obtained from the experiments made with the samples produced with microwave assisted combustion method under the same experimental conditions. The results show that cobalt aluminate nanoparticles synthesized by microwave assisted combustion exhibit a better photocatalytic activity. In experiments performed with samples produced via microwave-assisted combustion method, all dyestuff content in the solution containing 50 mg/L dye was completely removed under UV irradiation for approximately 60 min. It was determined that the catalyst dosage had an effect on the reaction rate and the reaction was found to be compatible with the pseudo first order kinetic model.
AtıfScopus12WoS12OpenAlex13İncele - MakaleAçık Erişim2019Scopus SJRQ2Antimony removal from aqueous solutions using magnetic nickel ferrite (NiFe 2 O 4 ) nanoparticles
Karcioğlu Karakaş, Zeynep; Boncukcuoğlu, Recep; Karakaş, İbrahim Hakkı
In this study, magnetic nickel ferrite (NiFe 2 O 4 ) nanoparticles were synthesized via microwave assisted combustion method and these particles were used as adsorbent for antimony removal. The most effective parameters for the removal efficiency are adsorbent dosage and temperature, while the impact of pH is insignificant. In order to determine the most suitable kinetic model, the compatibility of pseudo-first order, pseudo-second order and the intraparticle diffusion model was compared and the most suitable kinetic model was determined to be pseudo-second-order. Langmuir and Freundlich isotherms were assessed and the most suitable isotherm was observed to be Freundlich model.
AtıfScopus6WoS3OpenAlex6İncele - MakaleYalnız künye2017Scopus SJRQ2Adsorptive properties of As(III) from aqueous solution using magnetic nickel ferrite (NiFe2O4) nanoparticles: Isotherm and kinetic studies
Karcioğlu Karakaş, Zeynep; Boncukcuoğlu, Recep; Karakaş, İbrahim Hakkı
As(III) adsorption on NiFe2O4 nanoparticles were systematically investigated by controlling parameters such as stirring rate, pH, initial arsenic concentration, contact duration, temperature, and adsorbent dose. It was observed that the amount of adsorbed arsenic concentration is strongly depended on pH and temperature. The temperature and pH give rise to significant changes in the amount of adsorbed arsenic. As compared with Langmuir and Freundlich isotherms models, the latter is found to be well suited. Pseudo-first order, pseudo-second order, and intraparticle diffusion models were applied to adsorption equilibrium data obtained from the analysis of arsenic with diverse amount of initial concentration.
AtıfScopus12WoS13OpenAlex11İncele