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- MakaleAçık Erişim2015Scopus SJRQ2Simultaneous separation and preconcentration of Cd(II), Co(II), and Ni(II) ions in environmental samples by carrier element-free coprecipitation method prior to their flame atomic absorption spectrometric determination
Duran, Celal; Ozdes, Duygu; Akcay, Hakki Turker; Serencam, Huseyin; Tufekci, Mehmet
ABSTRACT: In the present study, Cd(II), Co(II), and Ni(II) ions were separated and preconcentrated via carrier element-free coprecipitation (CEFC) method by using an organic coprecipitating agent, 1,2-bis-(2-tosyl ethoxy) benzene (BTEB), prior to their flame atomic absorption spectrometric (FAAS) detections. The experimental conditions were optimized in terms of pH of the aqueous solution, BTEB amount, standing time, centrifugation rate and time, and sample volume. Under the optimum experimental conditions, the detection limits for Cd(II), Co(II), and Ni(II) ions were found to be 0.13, 0.67, and 0.46 μg L−1, respectively, and the relative standard deviations for the analyte ions were found to be lower than 4.0%. The accuracy of the method was tested by analyzing certified reference material and spike tests. The method was applied to determine the levels of Cd(II), Co(II), and Ni(II) ions in sea and stream water, macaroni, red lentil, and cracked wheat samples.
AtıfScopus17WoS16OpenAlex16
İncele - MakaleAçık Erişim2014Scopus SJRQ1Simultaneous separation and preconcentration of Ni(II) and Cu(II) ions by coprecipitation without any carrier element in some food and water samples
Duran, Celal; Tumay, Sureyya O.; Ozdes, Duygu; Serencam, Huseyin; Bektas, Hakan
A simple and highly sensitive separation and preconcentration procedure, which has minimal impact on the environment, has been developed. The procedure is based on the carrier element-free coprecipitation of Ni(II) and Cu(II) ions by using 2-{4-[2-(1H-Indol-3-yl)ethyl]-3-(4-chlorobenzyl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl}-N′-(pyrrol-2-ylmethyliden)acetohydrazide (ICOTPA), as an organic coprecipitant. The levels of analyte ions were determined by flame atomic absorption spectrometry. The detection limits for Ni(II) and Cu(II) ions were found to be 0.27 and 0.58 μg L-1, respectively, and the relative standard deviations for the analyte ions were lower than 4.0%. Spike tests and certified reference material analyses were performed to validate the method. The method was successfully applied for the determination of Ni(II) and Cu(II) ions levels in sea and stream water as liquid samples and red lentil and rice as solid samples.
AtıfScopus26WoS23OpenAlex26İncele - MakaleAçık Erişim2013Scopus SJRQ3Solid phase extraction of Cd(ii) and pb(ii) ions by a new carbothioamide derivative
Ozdes, Duygu; Duran, Celal; Bayrak, Hacer; Serencam, Huseyin; Basri Senturk, Hasan
An effective, simple, low cost and accurate sorption-spectrophotometric platform for the extractions and subsequent quantifications of Cd(II) and Pb(II) ions in food and environmental samples has been described in this dissertation. The separation and preconcentration of the analyte ions were accomplished by solid phase extraction method based on the adsorption of their N-(4-methylphenyl)-2-{[(4-phenyl-5-pyridin-4-yl-4H-1,2,4-triazol-3-yl)thio] acetyl} hydrazinecarbothioamide (MFPTAHK) complex on Amberlite XAD-8 resin in a mini column. The developed method was systematically investigated in different set of experimental parameters that influence the separation and preconcentration of Cd(II) and Pb(II) ions. The precision of the method was determined by reproducibility studies and expressed as relative standard deviations (RSD %) which were less than 4% for both analyte ions. The limits of detections (LODs) for Cd(II) and Pb(II) ions based on the three times the standard deviation of the blanks (N:10) were found to be 0. 31 ?g L-1 and 0. 86 ?g L-1, respectively. The developed SPE procedure was utilized for the simultaneous extraction and determinations of Cd(II) and Pb(II) ions levels in rice, cracked wheat and red lentil as food samples and various water samples.
AtıfScopus5WoS4OpenAlex5İncele - MakaleYalnız künye2013Scopus SJRQ3Application of carrier element free coprecipitation (CEFC) method for determination of Co(II), Cu(II) and Ni(II) ions in food and water samples
Serencam, Huseyin; Duran, Celal; Ozdes, Duygu; Bektas, Hakan
A simple and highly sensitive separation and preconcentration procedure, which has minimal impact on the environment, has been developed. The procedure is based on the carrier element free coprecipitation (CEFC) of Co(II), Cu(II), and Ni(II) ions by using 2-{4-[2-(1H-indol-3-yl)ethyl]-3-(4-methylbenzyl)-5-oxo- 4,5-dihydro-1H-1,2,4-triazol- 1-yl}-N'-(pyridin-2-yl methylidene)acetohydrazide (IMOTPA), as an organic coprecipitant. The levels of analyte ions were determined by flame atomic absorption spectrometry (FAAS). The detection limits for Co(II), Cu(II) and Ni(II) ions were found to be 0.40, 0.16 and 0.17 μg L-1, respectively, and the relative standard deviations for the analyte ions were lower than 3.0%. Spike tests and certified reference material analyses were performed to validate the method. The method was successfully applied for the determination of Co(II), Cu(II) and Ni(II) ions levels in sea and stream water as liquid samples and red pepper, black pepper, and peppermint as solid samples.
AtıfScopus10WoS10
İncele - MakaleYalnız künye2013Scopus SJRQ2Separation and pre-concentration of palladium(II) from environmental and industrial samples by formation of a derivative of 1,2,4-triazole complex on Amberlite XAD-2010 resin
Serencam, Huseyin; Bulut, Volkan Numan; Tufekci, Mehmet; Gundogdu, Ali; Duran, Celal; Hamza, Sibel; Soylak, Mustafa
A simple separation/pre-concentration method was developed for extraction of Pd(II) in various environmental samples, based on its adsorption of 4-phenyl-5-{[(4-phenyl-5-pyridin-4-yl-4H-1,2,4-triazole-3-yl)thio]methyl}-4H-1,2,4-triazole-3-thyol (PPTTMET) complex on Amberlite XAD-2010 resin in a mini column. The ligand has high affinity for Pd(II) among many other metals that are taken into consideration. The flame atomic absorption spectrometry is employed to determine the concentration of Pd(II). The optimum working conditions which were determined are as follows: 0.05 mol L-1 HNO3 as working medium, 1.0 mol L-1 HCI in acetone as elution solvent, 0.75 mg of PPTTMET amount and 750 mL of sample volume. The system was independent from the flow rates between 3.1 and 23.1 mL min-1. The Pd(II) adsorption capacity of Amberlite XAD-2010 resin was found to be 12.8 mg g-1 and the enrichment factor was calculated as 375. The method was successfully applied for the determination of Pd(II) in motorway dust samples, anodic sludge, gold ore, industrial electronic waste materials and various water samples.
AtıfScopus17WoS15OpenAlex17İncele