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Yayınlar
- MakaleYalnız künye2023Scopus SJRQ3The effects of heat treatment temperatures on photocatalytic activity of cobalt ferrite nanoparticles synthesised by microwave-assisted combustion method
Karakaş, Ibrahim Hakki; Karcioğlu Karakaş, Zeynep
In this study, the effects on the photocatalytic activities of particles after heat treatment has been applied to cobalt ferrite nanoparticles produced by microwave-assisted combustion method were observed. The heat treatment applied to the samples was produced with only the microwave effect, at temperatures ranging from 300 to 1000°C. Thermogravimetric analysis was performed on the precursor sample in air atmosphere. During this analysis, the gases released up to 1200°C were identified with a Fourier-transform infrared (FTIR) spectrometer integrated into a thermogravimetric analysis system. Then, the cobalt ferrite nanoparticles produced with heat treatments applied at various temperatures were used as a photocatalyst to remove the dyestuff content in synthetic wastewaters prepared by using Astrazon Red GTL textile dye by photocatalytic oxidation, and their photocatalytic activities were compared. In these experiments, the operational parameters for photocatalysis processes were applied as 400 rpm for stirring speed, 50 mg/L for initial contaminant concentration, 0.5 g/L for catalyst dosage, 25°C for temperature, and 4400 μW/cm2 for light intensity. As a result of the experiments, it was observed that the crystal structure of the cobalt ferrite nanoparticles produced with the increase of the applied heat treatment temperature improved significantly. The obtained data show a strong relationship between the structural properties of materials and their photocatalytic activities. In addition, it was determined that the dyestuff in the solution was completely degraded in the experiments, and it was determined that all processes were compatible with the pseudo-first-order kinetic model.
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İncele - MakaleAçık Erişim2019Scopus SJRQ2Antimony removal from aqueous solutions using magnetic nickel ferrite (NiFe 2 O 4 ) nanoparticles
Karcioğlu Karakaş, Zeynep; Boncukcuoğlu, Recep; Karakaş, İbrahim Hakkı
In this study, magnetic nickel ferrite (NiFe 2 O 4 ) nanoparticles were synthesized via microwave assisted combustion method and these particles were used as adsorbent for antimony removal. The most effective parameters for the removal efficiency are adsorbent dosage and temperature, while the impact of pH is insignificant. In order to determine the most suitable kinetic model, the compatibility of pseudo-first order, pseudo-second order and the intraparticle diffusion model was compared and the most suitable kinetic model was determined to be pseudo-second-order. Langmuir and Freundlich isotherms were assessed and the most suitable isotherm was observed to be Freundlich model.
AtıfScopus6WoS3OpenAlex6İncele - MakaleYalnız künye2017Scopus SJRQ2Adsorptive properties of As(III) from aqueous solution using magnetic nickel ferrite (NiFe2O4) nanoparticles: Isotherm and kinetic studies
Karcioğlu Karakaş, Zeynep; Boncukcuoğlu, Recep; Karakaş, İbrahim Hakkı
As(III) adsorption on NiFe2O4 nanoparticles were systematically investigated by controlling parameters such as stirring rate, pH, initial arsenic concentration, contact duration, temperature, and adsorbent dose. It was observed that the amount of adsorbed arsenic concentration is strongly depended on pH and temperature. The temperature and pH give rise to significant changes in the amount of adsorbed arsenic. As compared with Langmuir and Freundlich isotherms models, the latter is found to be well suited. Pseudo-first order, pseudo-second order, and intraparticle diffusion models were applied to adsorption equilibrium data obtained from the analysis of arsenic with diverse amount of initial concentration.
AtıfScopus12WoS13OpenAlex11İncele