İlgi alanları

• MakaleYalnız künye2024/r/bayburt/13044
  Effect of oxidation on radiation shielding capacity of ZrNbTaMoW Refractory High Entropy Alloys (RHEA) for nuclear reactor applications: Experimental and theoretical assessment

  Sakar, E.; Guler, O.; Alim, B.; Guler, S.H.; Dikici, B.; Lampke, T.

  This study presents the production and comprehensive assessment of a Refractory High Entropy Alloy (RHEA) with a ZrNbTaMoW composition for possible usage nuclear reactor applications. The alloy was synthesized using the mechanical alloying (MA) method, and its radiation properties were examined. Elemental powders of Zr, Nb, Ta, Mo, and W were utilized in equimolar quantities during the 120-hour MA process, conducted under a high-purity Ar atmosphere to prevent oxidation. The obtained HEA was then subjected to a mechano-thermal process to transform it into Refractory High-Entropy Oxide (RHEO) for comparing their radiation-shielding performance under oxide conditions. The characterization of the produced alloys through X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron dispersive spectroscopy (EDS). The photon shielding parameters of the alloys were experimentally obtained for various energies emitted from a 133Ba radioactive source, employing a Canberra UltraLEGe semiconductor detector. Furthermore, theoretical calculations were performed to validate the experimental data and to evaluate the alloys' photon shielding capabilities comprehensively. For this purpose, Phy-X/PSD software was employed to determine mass attenuation coefficients, half-value layer, effective atomic number, and effective electron density. Fast neutron absorption capabilities were determined through the calculation of average absorption cross-sections in the 2–12 MeV energy range. The results showed that the oxidation process significantly diminished the photon absorption capacity of RHEA.

  AtıfScopus34·WoS33

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• MakaleYalnız künye2023/r/bayburt/13052
  A comprehensive study on structural properties, photon and particle attenuation competence of CoNiFeCr-Ti/Al high entropy alloys (HEAs)

  Sakar, Erdem; Guler, Omer; Alım, Bünyamin; Say, Yakup; Dikici, Burak

  It is well known that high entropy alloys (HEAs) have a wide range of potential applications as radiation shielding due to their superior properties. The CoNiFeCr-Ti/Al compositions were chosen for their low cost as HEA in this study. The HEAs were successfully produced using the mechanical alloying (MA) method with equimolar CoNiFeCr, CoNiFeCrAl, and CoNiFeCrTi compositions. The production and structural properties of the alloys were investigated in detail. Besides, the photon and particle radiation shielding properties of the HEAs were calculated with the help of Phy-X/PSD, SRIM (10 keV-20 MeV), and ESTAR (10 keV-20 MeV) programs. The photon-matter interaction parameters were calculated in both specific photon energies emitted from 241Am, 133Ba, 109Cd, 60Co, 137Cs, 131I, and 22Na nuclides and a continuous energy range of 15 keV-15 MeV. The characterization of the alloys was investigated by using X-ray diffraction (XRD) and scanning electron microscopes (SEM) attached to an energy dispersive spectroscopy (EDX). It was found that the HEAs have a highly amorphous structure due to the selected production method. The crystal size of the alloys was calculated as 70, 35, and 20 nm for CoNiFeCr, CoNiFeCrAl, and CoNiFeCrTi, respectively. In terms of shielding properties, it has been determined that the produced HEAs have better shielding characteristics for photon and particle radiations than standard shielding concretes. In addition, the results demonstrated that CoNiFeCr alloy, which has the best shielding ability among the HEA alloys, can be used as a shielding material application requiring photon, electron, proton, alpha, and neutron radiations.

  AtıfScopus30·WoS32

  İncele
• MakaleYalnız künye2023/r/bayburt/11670
  An extensive survey on radiation protection features of novel hafnium iron-borophosphate glasses: Experimental and theoretical study

  Şakar, Erdem; Alım, Bünyamin; Ertap, Hüseyin; Karabulut, Mevlut

  This study aimed to determine the radiation (photon and particle) attenuation abilities of Hf added iron-borophosphate glasses considered as a candidate host matrix for Pu containing nuclear waste. Experimental absorption parameters were measured using 133Ba radionuclide for photon radiation, and the same parameters were theoretically calculated using Phy-X/PSD. The obtained data were evaluated comparatively for all glasses depending on the Hf and B contents. It has been determined that all of the glasses examined have photon absorption ability at a level that can be a shielding material for nuclear applications. In addition, the interaction cross-sections with particle radiations were computed using SRIM and ESTAR software. When the data obtained are evaluated thoroughly, it can be said that investigated glasses can be used as shielding in areas that require protection from both photon and particle radiation, in addition to being a candidate material for the vitrification of nuclear wastes containing Pu.

  AtıfScopus5·WoS6

  İncele
• MakaleYayıncıda açık erişim2023/r/bayburt/11012
  Determination of the molecular structure and spectroscopic properties of capsaicin

  Çınar, Mehmet; Alım, Bünyamin; Alım, Zuhal; Şakar, Erdem

  In this study, the ground state molecular structure and spectroscopic features of cis- and trans-forms of capsaicin were investigated using DFT (B3LYP) invoking 6–311++G(d,p) basis set. The optimized geometry of capsaicin was determined for the isolated molecule in a vacuum, and then the vibrational spectra –IR and Raman-were obtained, and the assignments of fundamental vibrational modes were done. By applying the GIAO method, proton and carbon chemical shifts were computed for the gas and solvated phases. Besides using the TD-DFT, the Hirshfeld surface and Molecular Electrostatic Potential surfaces were obtained and evaluated to understand the electronic properties. The Total and partial density of state (TDOS and PDOS) spectra were also examined. All obtained computational results were compared with the previously reported experimental data. A high accuracy was obtained for the ground state geometrical structure, and thus, the vibrational frequencies especially lie on the finger print region are predicted also with a high correlation. Similarly, the optimization of chemical shift values calculated by considering solvent effects with experimental data were found as high R2 values of 0.9953 and 0.9455 for C and H atoms, respectively. This comparison shows that the DFT method precisely predicts capsaicin's molecular and spectroscopic characteristics.

  AtıfScopus16·WoS16

  İncele
• MakaleYayıncıda açık erişim2022/r/bayburt/13441
  Precipitation-hardening stainless steels: Potential use radiation shielding materials

  Alım, Bünyamin; Özpolat, Özgür Fırat; Şakar, Erdem; Han, İbrahim; Arslan, İbrahim; Singh, V.P.; Demir, Lütfü

  In this study, it was focused on the research of new materials with high attenuation efficiency that can be used as radiation shielding material due to the incapability of conventional materials. In accordance with this purpose, the radiation shielding capabilities of four different precipitation-hardening stainless steels (PH-SSs), which are symbolized 15-5PH, 15-7PH, 17-4PH and 17-7PH, were determined both experimentally and theoretically in a wide range of radiation energy. For experimental measurements, two different detectors (Si(Li) and Na(Tl)) and twenty-three different photon energies (from 22.1 to 1332.5 keV) emitted from seven different radionuclides were used in narrow-beam transmission geometry. Phy-X/PSD software were used for theoretical calculations. The theoretically calculated parameters were determined both in the photon energies emitted by the radionuclides used in the experiment and in the continuous energy range of 0.015–15 MeV. Furthermore, in order to make a remarkable assessment of the integration of PH-SSs to nuclear energy applications, the all results obtained have been compared with the corresponding values of Fe-based steel concretes (steel-scrap (SS) and steel-magnetite (SM)), which are widely used as conventional shield materials in nuclear power plants. Moreover, in order to choose the best material to be used in nuclear applications among the PH-SSs, the results were evaluated comparatively in terms of both the characteristics of the materials and the magnitude of the radiation shielding parameters. Consequently, it was concluded that the material with the best radiation shielding performance among the examined PH-SSs was 15-7PH and the radiation shielding performance ranking was generally in the form of 15-7PH ≥ 15-5PH > 17-4PH > 17-7PH > SM > SS. Due to both high attenuation efficiency and superior properties for radiation shielding, it was determined that the PH-SSs can be used as new shielding materials in nuclear applications.

  AtıfScopus25·WoS25

  İncele
• MakaleYalnız künye2022/r/bayburt/13347
  Evaluation of γ-rays and neutron shielding parameters of high dense bismo-boro-tellurite glasses: Comparative study

  Şakar, E.; Özpolat, Ö.F.; Alım, B.; Alsaif, Norah A.M.; Rammah, Y.S.

  The main high energy radiation-matter interaction parameters of the 30B2O3-(70-x)TeO2-xBi2O3, where x = 40, 50, 60 and 70 mol% (BTB) glasses have been studied in the wide energy range. The theoretical calculations were made for some special X and γ-ray energies emitted from Fe (55), Am (241), Cs (137) and Co (60) radioactive sources for photon energies in the range of 15 keV - 15 MeV. All evaluated radiation shielding parameters were compared with some selected concretes (Ordinary concrete (OC), Hematite-Serpenite (HS) and Basalt-Magnetide (BM)), and glasses (Te and Pb based). The BTB- glasses have higher mass attenuation coefficient (MAC) values than other glasses (Te and Pb based) and concretes (OC, HS, and BM). The half value layer (HVL) of the investigated BTB-glasses has the following trend: OC > HS > BM > Te-Glass > Pb-glass > BTB40 > BTB50 > BTB60 > BTB70. In terms of mean free path (MFP), the BTB70 coded glass has the lowest MFP values due to the highest Bi2O3 content. In terms of the Zeff values of BTB coded glasses vary between 70 and 75 at the lowest energy level. The effective atomic number (Zeff) values in this energy region were 48.974 and 63.102 for Te and Pb glasses, respectively, and 13,339, 15.520 and 15.894 for OC, HS and BM concretes. The BTB-coded glasses have lower exposure buildup factor (EBF) than all other glass and concrete up to 3 MeV photon energies. The energy absorption buildup factor (EABF) values range from 1 to 4.2 for all samples at 1 MFP and at 40 MFP values, it reaches 108 for BTB coded glasses and 1010 for Te-based glass. Results confirmed that BTB- glasses, especially BTB70 glass sample can be used in applications requiring radiation safety.

  AtıfScopus17·WoS16

  İncele
• MakaleYayıncıda açık erişim2022/r/bayburt/12862
  Evaluation of photon interaction parameters of Anti-HIV drugs

  Akbaba, Uğur; Şakar, Erdem; Abu Al-Sayyed, Mohammed Ibrahim; Alim, Bünyamin; Özpolat, Özgür Fırat

  Medical treatment inevitably exposes individuals to radiation, including those taking drugs used to treat and prevent human immunodeficiency virus (HIV). Motivated by this, we investigated the radiation interaction properties of several HIV drugs to determine the interaction parameters, mass attenuation coefficient (MAC), atomic cross section (ACS), electronic cross section (ECS), effective atomic numbers (Zeff), and effective electron density (Neff). We calculated the values using the Phy-X/PSD software in the range of 0.015–15 MeV. Additionally, we calculated the exposure build-up factor (EBF), and energy absorption build-up factor (EABF) values of the drugs up to 40 mean free path (MFP) using the geometric progression (G-P) method. From our findings, we determined that Combivir, with its relatively high heavy element content, had the highest radiation attenuation capacity, whereas the probability of Lopinavir interacting with photons was the lowest compared with the other drugs. The results of the EBF and EABF parameters, including the scattering effects, ordered the drugs opposite to the primary interaction parameters such as MAC, ACS, ECS, and Zeff. These findings can guide the treatment process of HIV-positive patients and inform HIV prevention practices conducted alongside radiotherapy, as the interaction between radiation and a drug may cause deterioration in the drug's structure.

  AtıfScopus9·WoS8

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• MakaleYalnız künye2021Scopus SJRQ3/r/bayburt/10783
  Development of SiO2 based doped with LiF, Cr2O3, CoO4 and B2O3 glasses for gamma and fast neutron shielding

  Aygün, Bunyamin; Sakar, Erdem; Karabulut, Abdulhalik; Alim, Bunyamin; Sayyed, Mohammed, I; Singh, Vishwanath P.; Yorgun, Nergiz Yildiz; Özpolat, Ozgur Firat

  In this study, the fast neutron and gamma-ray absorption capacities of the new glasses have been investigated, which are obtained by doping CoO,CdWO4,Bi2O3, Cr2O3, ZnO, LiF,B2O3 and PbO compounds to SiO2 based glasses. GEANT4 and FLUKA Monte Carlo simulation codes have been used in the planning of the samples. The glasses were produced using a well-known melt-quenching technique. The effective neutron removal cross-sections, mean free paths, half-value layer, and transmission numbers of the fabricated glasses have been calculated through both GEANT4 and FLUKA Monte Carlo simulation codes. Experimental neutron absorbed dose measurements have been carried out. It was found that GS4 glass has the best neutron protection capacity among the produced glasses. In addition to neutron shielding properties, the gamma-ray attenuation capacities, were calculated using newly developed Phy-X/PSD software. The gamma-ray shielding properties of GS1 and GS2 are found to be equivalent to Pb-based glass.

  AtıfScopus19·WoS19

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• MakaleYalnız künye2021/r/bayburt/13472
  Determination of radioprotective and genotoxic properties of sulfamide derivatives

  Aygün, Bünyamin; Alaylar, Burak; Aklncloǧlu, Akln; Allm, Bünyamin; Kocaman, Ebu Talip; Karadayl, Mehmet; Abu Al-Sayyed, Mohammed Ibrahim; Aksu, Seyma; Sakar, Erdem; Özpolat, Özgür Flrat

  Some potential drug active substances with the ability to reduce the effects of radiation on human tissues and cells were investigated. For this purpose, eight different types of sulfamide derivatives were synthesized and nuclear radiation protection parameters were determined. Neutron radiation reduction parameters such as the half-value layer effective removal cross-sections, mean free path, and the number of particles passing through the sample were determined with GEANT4 code. Additionally, the gamma radiation attenuation parameters of the materials examined were determined using Phy-X/PSD software in the energy area of 0.015-15 MeV. These parameters are the half-value layer, mass attenuation coefficient, mean free path, exposure buildup factor and effective atomic number. Neutron radiation absorption experiments were applied using an 241Am-Be fast neutron source. All results obtained for neutron radiation were compared with paraffin and water. It has been found that the ability of sulfamide derivatives to absorb these radiations is superior to reference materials. To determine whether these derivatives could have adverse effects on human health, their genotoxic potential was determined using the Ames/Salmonella bacterial reversion test. The results showed that these derivatives can be considered genotoxically safe in tests at concentrations up to 5 mM. Thus, it is suggested that the derivative materials examined in this study can be used as active substances for a drug to be made for protection against both neutron and gamma radiation.

  AtıfScopus10·WoS9

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• MakaleYalnız künye2021/r/bayburt/11967
  A surveying of photon and particle radiation interaction characteristics of some perovskite materials

  Şakar, Erdem; Alim, Bünyamin; Fırat Özpolat, Özgür; Ceviz Şakar, Betül; Baltakesmez, Ali; Akbaba, Uğur

  In this study, we aimed to determinate of the photon and particle radiation interaction parameters of six different perovskites to help use perovskite materials in radiation applications. The parameters that are aimed to be investigated are MAC, HVL, MFP, Zeff, Neff, Ceff and EBF for photons, range values for charged particles, and FNRCS values for neutrons. The photon-interaction parameters the FNRCS values of the perovskites were calculated using Phy-X/PSD software in the energy range of 1 keV–100 GeV for photons and at 4.5 MeV energy for neutrons, respectively. Moreover, the range values of the perovskites were calculated using SRIM Monte Carlo software (for H+ and He++ particles) and ESTAR NIST software (for electrons) in the energy range from 0.01 MeV to 20 MeV. In order to make a notable assessment about the radiation interaction possibilities of the perovskites, the results obtained were compared with some standard shielding materials. According to the results obtained for all radiation types examined, it was determined that all calculated parameters were strongly dependent on both the type and energy of the radiation and the type of material. Additionally, it was observed that the order of preference of the examined materials as armor material in radiation applications varies according to the radiation type and energy. Consequently, it was determined that while the most suitable material in terms of photon shielding is P6 (Cs2SnI6) inorganic perovskite among the perovskites examined, this sample is not suitable material for neutron shielding applications.

  AtıfScopus27·WoS25

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