Yazarlar

• Demirtas, M.(4)
• Purcek, G.(4)
• Yanar, H.(4)
• Demirtas, Muhammet(1)
• Itoh, G.(1)
• Kaibyshev, R.(1)
• Kawasaki, M.(1)
• Purcek, Gencaga(1)
• Saray, Onur(1)
• Sato, E.(1)
• Taleff, E.M.(1)
• Tikhonova, M.(1)
• Yanar, Harun(1)
• Zhang, Z. F.(1)
• Zhang, Z. J.(1)
• Zhang, Z.F.(1)
• Zhang, Z.J.(1)

• MakaleAçık Erişim2018Scopus SJRQ3/r/bayburt/13676
  Effect of long-term natural aging on microstructure and room temperature superplastic behavior of UFG/FG Zn-Al alloys processed by ECAP

  Demirtas, M.; Yanar, H.; Purcek, G.

  Two potential superplastic compositions of Zn-Al alloy systems, Zn-22Al and Zn-0.3Al alloys, were chosen and processed by equal-channel angular pressing/extrusion (ECAP/E) in order to achieve high strain rate (HSR) superplasticity at room temperature (RT). ECAP-processed samples of both alloys were then subjected to long-term natural aging up to 1100 days to evaluate the effect of long-term natural aging on their microstructures and superplastic behaviors. Before natural aging, the maximum elongations to failure at RT were 400% for ultrafine-grained (UFG) Zn-22Al at the strain rate of 5 × 10 −2 s −1 and 1000% for fine-grained (FG) Zn-0.3Al at the strain rate of 1 × 10 −4 s −1 . Long-term natural aging did not cause a significant change in the elongation of UFG Zn-22Al alloy with 355% maximum elongation. However, optimum strain rate giving the maximum elongation decreased to 3 × 10 −3 s −1 . On the other hand, Zn-0.3Al alloy lost more than half of its superplastic elongation and showed an elongation to failure of 435% at the end of the natural aging period of 1100 days. Microstructural analyses show that grain boundary corrosion occurred in dilute Zn-0.3Al alloy during the natural aging process. Corroded grain boundaries resulted in cavity nucleation during the tensile tests and some of these cavities attained large sizes and caused premature failure.

  AtıfScopus4·WoS4·OpenAlex4

  İncele
• MakaleYalnız künye2018Scopus SJRQ1/r/bayburt/12479
  High temperature superplasticity and deformation behavior of naturally aged Zn-Al alloys with different phase compositions

  Demirtas, M.; Kawasaki, M.; Yanar, H.; Purcek, G.

  Two Zn-Al alloys, eutectoid Zn-22Al and dilute Zn-0.3Al, were processed through equal-channel angular pressing (ECAP). The ECAP-processed alloys were subjected to long-term natural aging at room temperature for 120 days in order to investigate the effect of long-term natural aging on high-temperature superplasticity and the deformation behavior of these alloys. The grain size of the Zn-22Al alloy increased from 200 nm after ECAP to 400 nm after the natural aging process. The Zn-0.3Al alloy with a grain size of 1.3 µm after ECAP demonstrated a reasonably stable microstructure with the grain size of ~ 1.7 µm after long-term natural aging. The naturally aged ultrafine-grained (UFG) Zn-22Al alloy showed an excellent superplastic elongation of about 1800% at 200 °C. Grain boundary sliding was determined as the dominant deformation mechanism in this alloy. On the contrary, a considerably low elongation to failure of 230% was recorded in the naturally aged fine-grained (FG) Zn-0.3Al alloy at 150 °C, and dislocation creep was evaluated as the main deformation mechanism for this alloy. Detailed microstructural analyses showed that the FG Zn-0.3Al alloy was exposed to grain boundary corrosion during the natural aging process due to the presence of Al precipitates at grain boundaries whereas such formation was not observed in the UFG Zn-22% Al alloy. Grain boundary sliding was hindered by grain boundary corrosion and the cavity nucleation at the corroded grain boundaries caused a premature failure leading to such a low elongation in the Zn-0.3Al alloy.

  AtıfScopus30·WoS30·OpenAlex33

  İncele
• BildiriAçık Erişim2018Scopus SJRQ3/r/bayburt/12241
  Room temperature superplasticity in fine/ultrafine-grained Zn-Al alloys with different phase compositions

  Demirtas, Muhammet; Yanar, Harun; Saray, Onur; Purcek, Gencaga; Kaibyshev, R.; Tikhonova, M.; Itoh, G.; Taleff, E.M.; Sato, E.

  Three Zn-Al alloys, namely Zn-22Al, Zn-5Al and Zn-0.3Al, were subjected to equal-channel angular pressing (ECAP), and the effect of ECAP on their microstructure and room temperature (RT) superplastic behavior were investigated in detail referring to previous studies reported by the authors of the current study. ECAP remarkably refined the microstructures of three alloys as compared to their pre-processed conditions. While the lowest grain size was achieved in Zn-22Al alloy as 200 nm, the grain sizes of Zn-5Al and Zn-0.3Al alloys were ~540 nm and 2 µm, respectively, after ECAP. After the formation of fine/ultrafine-grained (F/UFG) microstructures, all Zn-Al alloys exhibited superplastic behavior at RT and high strain rates. The maximum superplastic elongations were 400%, 520% and 1000% for Zn-22Al, Zn-5Al and Zn-0.3Al alloys, respectively. It is interesting to point out that the highest RT superplastic elongation was obtained in Zn-0.3Al alloy with the largest grain size, while Zn-22Al alloy having the lowest grain size showed the minimum superplastic elongation. This paradox was attributed to the different phase compositions of these alloys. The formation of Al-rich α/α phase boundaries, where grain boundary sliding is minimum comparing to Zn-rich η/η and η/α phase boundaries of Zn-Al alloys, is the lowest level in Zn-0.3Al alloy among all the alloys. Therefore, it can be concluded that if it is desired to achieve high superplastic elongation in Zn-Al alloys at RT, keeping Al content at a possibly minimum level seems to be the most suitable way.

  AtıfScopus6·OpenAlex5

  İncele
• MakaleYalnız künye2015Scopus SJRQ3/r/bayburt/14130
  Effect of Chemical Composition and Grain Size on RT Superplasticity of Zn-Al alloys processed by ECAP

  Demirtas, M.; Purcek, G.; Yanar, H.; Zhang, Z. J.; Zhang, Z. F.

  Dilute Zn-0.3Al, eutectic Zn-5Al and eutectoid Zn-22Al alloys were processed by multi-pass equal channel angular pressing (ECAP) in order to achieve fine grained (FG) or ultrafine-grained (UFG) microstructure and room temperature (RT) superplasticity. ECAP refined the microstructure of Zn-0.3Al and resulted in a FG Zn-rich.-matrix with an average grain size of 2 mu m and homogeneously distributed nano-sized Al-rich a-particles with the grain sizes in the range of 50-200 nm. A bi-modal microstructure was achieved in Zn-5Al alloy with UFG Al-rich a-and FG Zn-rich.-phases having mean grain sizes of 110 nm and 540 nm, respectively. ECAP brought about an agglomerate-free UFG microstructure in Zn-22Al alloy with an average grain size of 200 nm which is the lowest one obtained so far for this alloy after ECAP processing. The maximum RT superplastic elongations of 1000%, 520% and 400% were achieved for Zn-0.3Al, Zn-5Al and Zn-22Al alloys, respectively. Considering the RT superplasticity in Zn-Al alloys, it was found that lower Al content results in higher superplastic elongations even if the alloy has relatively larger grain size. Grain boundary sliding (GBS) was found to be the main deformation mechanism in region-II as the optimum superplastic region during RT deformation for all three Zn-Al alloys with the strain rate sensitivity factor ranging between 0.25-0.31.

  AtıfWoS19

  İncele
• MakaleAçık Erişim2015Scopus SJRQ1/r/bayburt/12329
  Achieving room temperature superplasticity in Zn-5Al alloy at high strain rates by equal-channel angular extrusion

  Demirtas, M.; Purcek, G.; Yanar, H.; Zhang, Z.J.; Zhang, Z.F.

  Multi-pass equal-channel angular extrusion/pressing (ECAE/P) was applied to the eutectic Zn-5Al alloy to achieve high strain-rate (HSR) superplasticity in that alloy at room temperature (RT) by producing ultrafine-grained (UFG) microstructure. ECAE processing transformed the coarse-grained lamellar/spherical microstructure into a unique bimodal structure having equiaxed Zn-rich η-phase with a mean grain size of 540 nm and spherical Al-rich α-phase with an average grain size of 110 nm. The α-phase particles accumulated mainly along the η-phase boundaries. This unique microstructure brought about an extraordinary improvement in HSR superplasticity of the alloy even at RT. While the strength values decreased after ECAE, the elongation to failure increased substantially. The maximum elongation was 520% at the strain rate of 10-3 s-1, still high elongation of about 400% was achieved at a high strain rate of 10-2 s-1. This extraordinary improvement in HSR superplasticity of Zn-5Al alloy was attributed to the morphologically unique bimodal microstructure in UFG regime formed after ECAE. The grain boundary sliding (GBS) was found to be the main deformation mechanism for this alloy in superplastic regime.

  AtıfScopus33·WoS35·OpenAlex34

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