Demirtas, Muhammet; Yanar, Harun; Saray, Onur; Purcek, Gencaga; Kaibyshev, R.; Tikhonova, M.; Itoh, G.; Taleff, E.M.; Sato, E.

Three Zn-Al alloys, namely Zn-22Al, Zn-5Al and Zn-0.3Al, were subjected to equal-channel angular pressing (ECAP), and the effect of ECAP on their microstructure and room temperature (RT) superplastic behavior were investigated in detail referring to previous studies reported by the authors of the current study. ECAP remarkably refined the microstructures of three alloys as compared to their pre-processed conditions. While the lowest grain size was achieved in Zn-22Al alloy as 200 nm, the grain sizes of Zn-5Al and Zn-0.3Al alloys were ~540 nm and 2 µm, respectively, after ECAP. After the formation of fine/ultrafine-grained (F/UFG) microstructures, all Zn-Al alloys exhibited superplastic behavior at RT and high strain rates. The maximum superplastic elongations were 400%, 520% and 1000% for Zn-22Al, Zn-5Al and Zn-0.3Al alloys, respectively. It is interesting to point out that the highest RT superplastic elongation was obtained in Zn-0.3Al alloy with the largest grain size, while Zn-22Al alloy having the lowest grain size showed the minimum superplastic elongation. This paradox was attributed to the different phase compositions of these alloys. The formation of Al-rich α/α phase boundaries, where grain boundary sliding is minimum comparing to Zn-rich η/η and η/α phase boundaries of Zn-Al alloys, is the lowest level in Zn-0.3Al alloy among all the alloys. Therefore, it can be concluded that if it is desired to achieve high superplastic elongation in Zn-Al alloys at RT, keeping Al content at a possibly minimum level seems to be the most suitable way.

AtıfScopus6·OpenAlex5

İncele

Demirtas, Muhammet; Purcek, Gencaga; Yanar, Harun; Zhang, Zhenjun; Zhang, Zhe-Feng; Sato, E.; Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo, Sagamihara, Kanagawa, 252-5210; Itoh, G.; Kobayashi, J.; Department of Mechanical Engineering, Ibaraki University, 4-12-1 Nakanarusawa, Hitachi, 316-8511

Zn–22Al alloy was processed using a well-designed two-step equal channel angular extrusion/pressing (ECAE/P), and ultrafine-grained (UFG) microstructure with 200 nm grain size was achieved. UFG Zn-22Al was subjected to long-term (up to 60 days) aging at room temperature (RT) and it was seen that natural aging caused limited grain growth in the microstructure. Grain sizes of about 300 nm, 350 nm and 350 nm were measured after 15, 30 and 60 days aging, which mean that UFG Zn-22Al alloy has a good microstructural stability at RT up to 60 days. ECAPed Zn-22Al alloy showed a maximum elongation of about 400% at a high strain rate of 5×10-2 s-1 and maximum elongation decreased with increasing grain size. Elongation to failures of ~375% and ~350% were obtained with the samples having 300 nm and 350 nm grain sizes, respectively. In addition, natural aging slightly decreased the strain rate at which superplastic region formed. While the maximum elongation occurred at the strain rate of 5×10-2 s-1 in ECAPed UFG alloy, it took place at lower strain rate of 1×10-2 s-1 after aging for all time periods. Also, flow stress of the alloy increased with increasing grain size during natural aging.

AtıfScopus7·OpenAlex8

İncele