Sürdürülebilir Kalkınma Amaçları
Yazarlar
Yayınlar
- MakaleAçık Erişim2022Scopus SJRQ1Techno-economic assessment of a synthetic fuel production facility by hydrogenation of CO2 captured from biogas
Tozlu, Alperen
In this study, a thermodynamic and economic analysis of a synthetic fuel production facility by utilizing the hydrogenation of CO2 captured from biogas is carried out. It is aimed to produce methanol, a synthetic fuel by hydrogenation of carbon dioxide. A PEM electrolyzer driven by grid-tie solar PV modules is used to supply the hydrogen need of methanol. The CO2 is captured from biogas produced in an actual wastewater treatment plant by a water washing unit which is a method of biogas purification. The required power which is generated by PV panels, in order to produce methanol, is found to be 2923 kW. Herein, the electricity consumption of 2875 kW, which is the main part of the total electricity generation, belongs to the PEM system. As a result of the study, the daily methanol production is found to be as 1674 kg. The electricity, hydrogen and methanol production costs are found to be $ 0.043 kWh−1, $ 3.156 kg−1, and $ 0.693 kg−1, respectively. Solar availability, methanol yield from the reactor, and PEM overpotentials are significant factors effecting the product cost. The results of the study presents feasible methanol production costs with reasonable investment requirements. Moreover, the efficiency of the cogeneration plant could be increased via enriching the biogas while emissions are reduced.
AtıfScopus34WoS32OpenAlex37
İncele - MakaleAçık Erişim2022Scopus SJRQ1Thermoeconomic analysis of a low-temperature waste-energy assisted power and hydrogen plant at off-NG grid region
Tozlu, Alperen; Kayabasi, Erhan; Ozcan, Hasan
In this study, thermoeconomic analysis of a CO2 power cycle and PEM hydrogen system using ultra-low temperature waste heat from a milk production facility is conducted. In the transcritical CO2 cycle, low-temperature LNG evaporation is used for cooling the condenser to increase the temperature difference enabling low temperature waste heat use. In addition, a PEM electrolyzer produces hydrogen to reduce the LNG requirement at the plant. A CO2-water exchanger has been designed to recover the pasteurized water's excess heat and evaporate the CO2 using Simcenter-Flomaster software. The inlet mass flow rates and outlet temperatures of the heat exchanger were optimized by performing thermoecomic analysis, and the thermal and economic performance of the facility was examined. The power cycle has 14% higher efficiency when LNG is used as the heat sink compared to ambient temperature condensation with an electricity production cost range at 0.05–0.11 $/kWh, and the hydrogen generation cost is between $2.6–5.20 kg−1. It is found that the plant could only be economically feasible when less than 50% of the power produced is used for hydrogen generation. Consequently, the proposed system can co-generate power and on-demand hydrogen in off-NG grid regions with reasonable investment and product costs.
AtıfScopus6WoS6OpenAlex8İncele - MakaleYalnız künye2019Scopus SJRQ1Hydrogen generation via the catalytic hydrolysis of morpholine-borane: A new, efficient and cost-effective hydrogen storage medium
Can, Hasan; Metin, Önder
Herein, for the first time, we introduce the morpholine-borane complex (MB) as a new, efficient, cost-effective and commercially available chemical hydrogen storage material for mobile applications. In this regard, hydrogen production from the hydrolysis of MB catalyzed by in situ generated water-soluble polymer stabilized Ag(0) and Pd(0) nanoparticles (NPs) is reported for the first time. In situ generated PSMA-stabilized Ag(0) and Pd(0) NPs showed remarkable activity in hydrogen production from the hydrolysis of MB at room temperature, providing initial TOFs of 16.1 min−1 and 37.3 min−1, respectively. A set of kinetic studies on the catalytic hydrolysis of MB were conducted by changing the catalyst/substrate amount and temperature, and the rate law expression and activation parameters were produced by collecting the kinetic data. The apparent activation energies for the in situ generated Ag(0) and Pd(0) NPs catalyzed MB hydrolysis were calculated to be 71.4 and 32.5 kJ mol−1, respectively.
AtıfScopus20WoS20OpenAlex22İncele