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- MakaleYalnız künye2026Scopus SJRQ1Upcycling marble waste into construction materials and heavy metal adsorbents via hot-pressed geopolymerization technique
Öksüzer, Nurullah; Uslu, Emin; Gökçe, H. Süleyman
This study presents a sustainable approach to utilizing marble dust waste by producing bifunctional metakaolin-based geopolymers via a synchronized hot-pressing technique. In this study, the environmental footprint was minimized by designing mixtures in which marble waste constituted 50% of the total volume. Three stoichiometric series were investigated by varying the activator modulus (SiO2/Na2O = 3 and 4) and the Si/Al ratio (2 and 3) under two curing temperatures (150 and 300 °C) and three compaction stresses (5, 25, and 50 MPa). Thus, a high-volume industrial byproduct was transformed into a functional component. In this context, it investigated the transformation of industrial products into next-generation materials by using them to produce cementless composite geopolymers for civil engineering and to adsorb heavy metal (Cu2+). As a result of the research, an early compressive strength of 58 MPa was obtained through heat treatment and pressing applied at 300 °C and 50 MPa. This optimum strength was achieved in the SiO2/Na2O = 3, Si/Al = 3 series, whereas excess silica (SiO2/Na2O = 4) and excess aluminum (Si/Al = 2) limited the strength to 16.8 and 35.2 MPa, respectively. Microstructural analyses (SEM/EDS and FT-IR) revealed that marble dust was used as a filler material in the microstructure to produce an N-A-S-H-containing matrix. The produced materials were then ground after their service life and used to purify water containing heavy metals. More than 99.75% of Cu2+ was removed through ion exchange between copper ions used as heavy metals. The residual Cu2+ concentration fell below 0.25 mg/L from an initial concentration of 100 mg/L, and the released Na+-to-adsorbed Cu2+ molar ratio of approximately 1.8–2.3 confirmed an ion-exchange-dominated uptake mechanism. This structural and environmental impact demonstrates that marble waste, which is otherwise discarded as waste, is considered inert, offering an alternative model for the circular economy and environmental applications.
- MakaleAçık Erişim2020Scopus SJRQ1Development of Eco-Efficient Fly Ash-Based Alkali-Activated and Geopolymer Composites with Reduced Alkaline Activator Dosage
Gökçe, H. S.; Tuyan, M.; Ramyar, K.; Nehdi, M. L.
The eco-efficiency and economy of geopolymer composites largely depend on their alkaline activator dosage. In this study, the effect of applying a pre-setting pressure and variation of the aggregate-to-fly ash ratio on the alkaline solution dosage and mechanical strength of fly ash-based geopolymer composites was explored. It is shown that through control of the aggregate-to-ash ratio and application of pre-setting pressure, compressive strength could be increased by 102% and 86% for Class F fly ash-based geopolymer and alkali-activated Class C fly ash-based mixture, respectively. The total alkaline solution consumption could be reduced from 718 to 188 kg/m(3) and from 769 to 262 kg/m3 for Class F fly ash-based geopolymer and alkali-activated Class C fly ash-based mixture, respectively. The proposed method reduced the alkaline solution consumption per compressive strength (6.2 kg.m(-3).MPa-1) by up to 85% compared to that of the reference manually consolidated control geopolymer. The findings demonstrate that fly ash-based geopolymers could be made more sustainable and eco-efficient through tailored production techniques. (C) 2019 American Society of Civil Engineers.
AtıfWoS23OpenAlex30
İncele - MakaleYalnız künye2016Scopus SJRQ1Properties of NaOH activated geopolymer with marble, travertine and volcanic tuff wastes
Tekin, Ilker
In this study, geopolymer composite pastes (GCM) were produced using wastes of marble, travertine and natural pozzolan, with 1 M, 5 M and 10 M NaOH as alkali-activator. Curing process were done at 20, 45 and 75 °C temperatures for 24 h in an oven. And after that GCMs were exposed to wet and dry condition separately. The strength tests were done on the 2nd, 3rd, 7th, 28th and 90th days of curing period. The compressive strengths of the specimens in the wet conditions were reduced depending on time, but in dry conditions were increased with curing time.
AtıfScopus137WoS117OpenAlex149
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