Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Gökçe, H.S.(2)
- Nehdi, M.L.(1)
- Tuyan, M.(1)
Yayınlar
- MakaleAçık Erişim2024Scopus SJRQ3Durability of slag-based alkali-activated materials: A critical review
Gökçe, H.S.
As the world becomes increasingly aware of the devastating effects of climate change, the need for sustainable building materials that are both durable and environmentally friendly increases. Geopolymer and alkali-activated materials formed by a chemical reaction between an alkaline activator solution and an aluminosilicate source have gained popularity in recent years. The alkaline activator solution dissolves the aluminosilicate source, which then undergoes a polycondensation reaction to form a three-dimensional geopolymeric gel network. The development of this network ensures the strength and durability of the material. Today, this phenomenon of durability has been studied in detail to enable the development of superior construction materials, taking into account degradation mechanisms such as carbonation, leaching, shrinkage, fire, freezing and thawing, and exposure to aggressive environments (chlorides, acids, and sulphates). Although there are many unsolved problems in their engineering applications, slag-based alkali-activated materials appear to be more advantageous and are promising as alternative materials to ordinary Portland cement. First of all, it should not be ignored that the cure sensitivity is high in these systems due to compressive strength losses of up to 69%. Loss of strength of alkali-activated materials is considered an important indicator of degradation. In binary precursors, the presence of fly ash in slag can result in an improvement of over 10% in compressive strength of the binary-based alkali-activated materials after undergoing carbonation. The binary systems can provide superior resistance to many degradation mechanisms, especially exposure to high-temperature. The partial presence of class F fly ash in the slag-based precursor can overcome the poor ability of alkali-activated materials to withstand high temperatures. Due to the desired pore structure, alkali-activated materials may not be damaged even after 300 freeze–thaw cycles. Their superior permeability compared to cementitious counterparts can extend service life against chloride corrosion by more than 20 times. While traditional (ordinary Portland cement-based) concrete remains the most widely used material in construction, geopolymer concrete’s superior performance makes it an increasingly emerging option for sustainable and long-lasting infrastructure.
AtıfScopus69WoS63OpenAlex70
İncele - Derleme MakaleAçık Erişim2021Scopus SJRQ1Alkali-activated and geopolymer materials developed using innovative manufacturing techniques: A critical review
Gökçe, H.S.; Tuyan, M.; Nehdi, M.L.
The manufacturing of geopolymers and alkali-activated materials for precast and cast in-situ construction applications could be achieved using suitable production techniques, such as one-part production, pre-setting pressure and hot pressing, two-stage concreting, and 3-dimensional printing. Adequate selection and tailoring of the manufacturing methodology are imperative for overcoming characteristic application problems of these materials and achieving eco-efficiency and superior engineering properties. With distinctive benefits including rapid solidification, lower cost, saving natural resources, less energy consumption, and reduced carbon footprint, alkali-activated and geopolymer composites have emerged as a strong contender for replacing conventional concrete in diverse construction applications. Critical analysis of the literature on innovative production methods indicates that the one-part production technique is promising for the eliminating design complexity of these mixtures. The pre-setting pressure and hot pressing applications would allow the achievement of superior physical and mechanical characteristics in a short period of time, especially for the precast industry. The workability and setting problems of alkali-activated materials could be overcome using the two-stage concreting methodology. To be used in 3D printing of alkali-activated and geopolymer materials, remarkable development is required in terms of rheological aspects. Accordingly, this paper surveys pertinent and recent literature and critically reviews the state-of-the-art of alternative production techniques of alkali-activated and geopolymeric materials, along with its use in recent applications, identifies pertinent knowledge gaps, and defines future research directions.
AtıfScopus155WoS137OpenAlex167İncele