Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2018Scopus SJRQ2Effect of doping concentration on the structural and optical properties of nanostructured Cu-doped Mn3O4 films obtained by SILAR technique
Bayram, Ozkan; Guney, Harun; Ertargin, Mehmet Emrah; Igman, Erdal; Simsek, Onder
In this study, the effect of Cu doping on the optical, structural and wettability properties of the nanostructured Cu-doped Mn3O4 (CMO) thin films obtained by using successive ionic layer adsorption and reaction technique was systematically investigated. The optical, morphological, structural and wettability properties of the nanostructured CMO films were determined using scanning electron microscopy (SEM), X-ray diffraction (XRD), UV–Vis spectroscopy, and water contact angle (WCA) measurements. There were significant differences in the crystal structure of the nanostructured CMO thin films. The Cu doping disrupted this structure of pure (undoped) Mn3O4 films and caused the formation of the porous structure. Optical properties such as extinction coefficient, refractive index, and dielectric constants and optical band gap, were determined for nanostructured CMO films. Compared with pure films, the band gap of Cu-doped films decreased from 2.06 to 1.71 eV with increasing Cu concentration. The dielectric constants of the films showed that the nanostructured CMO films have a transparent structure. At 300 nm wavelength, the dielectric constants of pure Mn3O4 films were 2.22 while the calculated dielectric constants at increasing doping concentrations were 3.55, 2.41 and 2.25. It was also found from the WCA measurements that the thin films were hydrophilic in character and the WCA values for the nanostructured CMO thin films were measured as 24, 29 and 40 of degree.
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İncele - MakaleAçık Erişim2018Scopus SJRQ2Effect of the number of cycles on the optical and structural properties of Mn3O4 nanostructures obtained by SILAR technique
Bayram, Ozkan; Simsek, Onder; Guney, Harun; Igman, Erdal; Murat Ozer, Mustafa
In this study, nanostructured Mn3O4 (manganese oxide) thin films were successfully obtained by successive ionic layer adsorption and reaction (SILAR) method on the soda lime glass substrates using Manganese Nitrate (Mn(NO3)2) and Ammonium hydroxide (NH4(OH)) as cationic and anionic precursors respectively. Structural and morphological characterizations of the Mn3O4 films obtained at different cycles were determined using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The crystal structure of the thin films were also confirmed by RAMAN spectroscopy. Optical properties such as absorption, transmission, reflection, extinction coefficient and optical band gap of nanostructured Mn3O4 thin films were determined by UV–Vis spectroscopy. SEM images showed that the manganese oxide nanosheets formed uniformly on substrate surface. As the deposition cycles increased, nano-sheets structure deteriorated. The optical band gap of Mn3O4 thin films varied from 2.12 to 2.59 eV, depending on the increase in number of cycles. From contact angle measurements of thin films, it was determined that thin films had hydrophilic character.
AtıfScopus14WoS14OpenAlex16İncele - MakaleAçık Erişim2018Scopus SJRQ2A study on the optical, chemical and dielectric properties of PPCIN thin films derived from essential oil compounds using RF plasma polymerisation technique
Bayram, Ozkan; Simsek, Onder
Polymer-based nanostructured films were produced on various substrates using Radio Frequency (RF) plasma polymerization technique from Cinnamaldehyde monomer which is an organic compound. To fabricate polymer thin film, the pressure, the deposition time and RF power were set to 480 mTorr, 30 min and 15, 20 and 30 W, respectively. The effect of RF power on the optical, morphological and chemical properties of thin films were investigated. The optical, morphological and chemical properties were determined by UV–Vis spectroscopy, Atomic Force Microscopy (AFM) and FTIR spectroscopy, respectively. The average surface roughness of thin films was detected as 5.7 nm, 3.9 nm and 11.7 nm using AFM depending on the increase in RF power. Using FTIR spectroscopy, the chemical structure of the polymer thin films was compared with that of the monomer material, and it was found that the majority of the functional groups belonging to the monomers also appeared in the thin films. Optical band gap of thin films increased with RF power and these values were determined as 2.83 eV, 3.05 eV and 2.98 eV, respectively. The extinction coefficients and refractive indices of the thin films were measured at 500 nm between 0.00183–0.00522 and 2.40–2.78, respectively.
AtıfScopus14WoS14OpenAlex16İncele - MakaleYalnız künye2018Scopus SJRQ2Determination of the optical and chemical properties of aniline doped plasma polymerized cineole thin films synthesized at various RF powers
Bayram, Ozkan
Aniline-doped plasma polymerized cineole (PPCin) thin films were produced on glass substrates by plasma polymerization technique under varying Radio Frequency (RF) power levels. PPCin thin films were produced at 30 min deposition time and at 50, 75 and 100 W RF energies. Surface morphologies of pure and aniline-doped PPCin thin films obtained on glass substrates were investigated by AFM. It was found that the average surface roughness of pure PPCin thin films increased from 0.19 to 30.6 nm due to the dopant effect and RF energies. The optical band gap for pure polymer thin film was 3.65 eV, but with the effect of doping, these value was found to be 3.54, 3.29 and 3.93, respectively, with increasing RF energy. The extinction coefficient and refractive indices of PPCin thin films were calculated as between 0.065 and 0.92 and between 1.24 and 1.57 respectively, at the wavelength of 400 nm. Wettability analyzes of PPCin thin films were also determined using the water contact angle (WCA) measurement and all thin films were found to have hydrophilic character.
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