• MakaleAçık Erişim2021Scopus SJRQ3
    Development of SiO2 based doped with LiF, Cr2O3, CoO4 and B2O3 glasses for gamma and fast neutron shielding

    Aygün, Bunyamin; Sakar, Erdem; Karabulut, Abdulhalik; Alim, Bunyamin; Sayyed, Mohammed, I; Singh, Vishwanath P.; Yorgun, Nergiz Yildiz; Özpolat, Ozgur Firat

    In this study, the fast neutron and gamma-ray absorption capacities of the new glasses have been investigated, which are obtained by doping CoO,CdWO4,Bi2O3, Cr2O3, ZnO, LiF,B2O3 and PbO compounds to SiO2 based glasses. GEANT4 and FLUKA Monte Carlo simulation codes have been used in the planning of the samples. The glasses were produced using a well-known melt-quenching technique. The effective neutron removal cross-sections, mean free paths, half-value layer, and transmission numbers of the fabricated glasses have been calculated through both GEANT4 and FLUKA Monte Carlo simulation codes. Experimental neutron absorbed dose measurements have been carried out. It was found that GS4 glass has the best neutron protection capacity among the produced glasses. In addition to neutron shielding properties, the gamma-ray attenuation capacities, were calculated using newly developed Phy-X/PSD software. The gamma-ray shielding properties of GS1 and GS2 are found to be equivalent to Pb-based glass.

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  • MakaleAçık Erişim2020Scopus SJRQ2
    Investigation of neutron and gamma radiation protective characteristics of synthesized quinoline derivatives

    Aygün, Bunyamin; Alaylar, Burak; Turhan, Kadir; Sakar, Erdem; Karadayi, Mehmet; Abu Al-Sayyed, Ibrahim; Pelit, Emel; Güllüce, Medine; Karabulut, Abdulhalik; Turgut, Zuhal

    Purpose: Quinoline is formed by various natural compounds, such as alkaloids from the cinchona plant, which exhibit various biological activities, and is an important building material for the development of new drugs. Quinoline can be used in anti-radiation drug development but radiation interaction properties must be determined. Material and methods: In this study, six types of synthesized quinoline derivatives were used. Fast neutron removal cross-section, mean free path, half value layer and transmission number were theoretically determined by using GEometry ANd Tracking 4 and FLUktuierende KAskade simulation codes for neutron shielding. Neutron dose absorption rates were determined using the(241)Am-Be fast neutron source and the Canberra NP series portable BF(3)gas proportional neutron detector. Gamma radiation shielding parameters were determined by using WinXCom and PSY-X/PSD software. Additionally, the genotoxic potentials of the derivatives were assessed by using the Ames/Salmonellabacterial reversion assay. Results and conclusions: Neutron shielding parameters such as removal cross-section, mean free path, half value layer and transmission number were theoretically determined for fast neutrons. To determine neutron absorption capacity of quinoline derivatives, neutron absorption, experiments were conducted. In addition, gamma radiation shielding parameters were calculated such as the mean free path (MFP), mass attenuation coefficient (mu t), half value thickness layer (HVL) and effective atomic number (Zeff) in the energy range of 0.015-15 MeV. The results of the all quinoline derivatives have excellent fast neutron shielding power compared to ordinary concrete. In addition, all quinoline derivatives have been found to have the capacity to attenuate gamma radiation. Moreover, they absorb well in both types of radiation, do not cause secondary radiation, and they are genotoxically safe at the tested concentrations. This study has demonstrated that these products can be used as active ingredients for a drug to be developed against radiation.

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  • MakaleYalnız künye2020Scopus SJRQ2
    Theoretical and experimental validation gamma shielding properties of B2O3-ZnO-MgO-Bi2O3 glass system

    Kaky, Kawa M.; Sayyed, M. I.; Khammas, Abbas; Kumar, Ashok; Sakar, Erdem; Abdalsalam, Alyaa H.; Sakar, Betul Ceviz; Alim, Bunyamin; Mhareb, M. H. A.

    In the present work, we fabricated a series of six glasses to be utilized in the field of radiation shielding application. Glasses have been synthesized using a melt-quenching ordinary technique. In this work, we investigated the structural properties of these glasses using Raman spectroscopy. Moreover, optical properties have been studied in the present work. The radiation attenuation ability for the present samples was also investigated and measured using transmission geometry between 81 and 964.1 keV. The mass attenuation coefficient was measured and the results were validated by the WinXcom program. Also, radiation protection efficiency (RPE) was evaluated and discussed in terms of photon energy and Bi2O3 concentration. From RPE curve, we found that the fabricated glasses can be used as effective shielding materials especially for the low energies (81-383 keV). The half value layer also was calculated and the results of this parameter showed that S6 (contains 60 mol% of Bi2O3) has the higher probability of the interaction with gamma photons, leading to less number of photons transmitted this sample and thus better photon attenuator.

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  • MakaleAçık Erişim2018
    Investigation of alloying effects on XRF parameters of 3d transition metals in Permendur49, Kovar and Ti50Co50 alloys

    Alim, Bunyamin; Ugurlu, Mine; Han, Ibrahim; Demir, Lutfu

    The alloying effects on X-ray fluorescence (XRF) parameters such as K shell fluorescence cross-sections (sigma(K alpha), sigma(K beta) and sigma(K)), K shell average fluorescence yields (omega(K)) and K to L shell vacancy transfer probabilities (eta(KL)) of V, Ti, Fe, Co and Ni 3d transition metals in Permendur49 (Fe49Co49V2), Kovar (Fe54Ni29Co17) and Ti50Co50 alloys have been carried out by X-ray fluorescence studies. K X-ray intensity ratios of these 3d transition metals in both pure form and present alloys have been measured following excitation by 22.69 keV X-rays from a 10 mCi Cd-109 radioactive point source. The characteristic K-X-ray spectra from samples were detected by a high-resolution Si(Li) solid-state detector. The investigated fluorescence parameters of present 3d transition elements in alloys indicate significant differences with respect to the pure metals. Consequently, the observed change of the investigated fluorescence parameters can be attributed to the delocalization and charge transfer phenomena between the 3d elements in alloys. (c) 2017 The Egyptian Society of Radiation Sciences and Applications. Production and hosting by Elsevier B.V.

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  • MakaleAçık Erişim2018
    Alloying effect on K shell X-ray fluorescence cross-sections and yields in Ti-Ni based shape memory alloys

    Alim, Bunyamin; Han, Ibrahim; Demir, Lutfu

    K shell X-ray fluorescence cross-sections (sigma(K alpha), sigma(K beta) and sigma(K)), and K shell fluorescence yields (omega(K)) of Ti, Ni both in pure metals and in different alloy compositions (TixNi1-x; x = 0.3, 0.4, 0.5, 0.6, 0.7) were measured by using energy dispersive X-ray fluorescence (EDXRF) technique. The samples were excited by 22.69 keV X-rays from a 10 mCi Cd-109 radioactive point source and K X rays emitted by samples were counted by a high resolution Si(Li) solid-state detector coupled to a 4 K multichannel analyzer (MCA). The alloying effects on the X-ray fluorescence (XRF) parameters of Ti-Ni shape memory alloys (SMAs) were investigated. It is clearly observed that alloying effect causes to change in K shell XRF parameter values in Ti-Ni based SMAs for different compositions of x. Also, the present investigation makes it possible to perform reliable interpretation of experimental sigma(K alpha), sigma(K beta) and omega(K) values for Ti and Ni in SMAs and can also provide quantitative information about the changes of K shell X-ray fluorescence cross sections and fluorescence yields of these metals with alloy composition. (c) 2017 The Egyptian Society of Radiation Sciences and Applications. Production and hosting by Elsevier B.V.

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