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- MakaleYalnız künye2019Scopus SJRQ2The relationship between the external magnetic field and K X-ray intensity ratios of immiscible MoxAg1-x alloys
Uğurlu, Mine; Alım, Bünyamin; Demir, Lütfü
Kβ/Kα intensity ratios were obtained for Molybdenum-Silver alloys produced in different concentration range in different magnetic fields. It was seen that these values without magnetic field were found slight different from each other for pure Mo, pure Ag, alloyed Mo and alloyed Ag. It was determined that Kβ/Kα intensity ratios change slightly by depending on alloying element composition and it was seen that Kβ/Kα intensity ratios of Mo and Ag are in the range of the literature valuesFurthermore, that these values have same direction with the changing of the magnetic field for all alloying composition may take us conclusion which alloys in different concentration may have same magnetic properties.
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İncele - MakaleAçık Erişim2017Scopus SJRQ1Delocalization and charge transfer studies of PERMENDUR49, KOVAR and Ti50Co50 alloys from relative K X-ray intensity ratios
Uğurlu, Mine; Alım, Bünyamin; Han, İbrahim; Demir, Lütfü
Kβ-to-Kα X-ray intensity ratios of Fe, Ni, Co, Ti, V in pure form and PERMENDUR49 (Fe49Co49V2), KOVAR (Fe54Ni29Co17) and Ti50Co50 alloys were calculated in order to determine valence-electron structure of the samples. The obtained experimental Kβ-to-Kα X-ray intensity ratios were found to be 0.1252 ± 0.0025, 0.1256 ± 0.0027, 0.1298 ± 0.0026, 0.1327 ± 0.0028, 0.1346 ± 0.0027 for pure Ti, V, Fe, Co and Ni, respectively. These values of present pure metals have increased with the increment in atomic number of these pure metals. Also, although the obtained these values for metal atoms in PERMENDUR49, Ti50Co50 and for Fe, Ni metal atoms in KOVAR approximately compatible with respect to results same pure metals, the obtained experimental Kβ-to-Kα X-ray intensity ratios for Co in KOVAR are significantly different from the appropriate values for pure Co metal. Then, the valence-electron populations of these alloys were calculated in order to answer as to why the characteristic properties of the studied alloys are distinct from each other. The valence-electron structures of these metals in pure form and alloys were determined by comparison of the calculated Kβ-to-Kα X-ray intensity ratios with the results of multi-configurations Dirac-Fock (MCDF) calculations to understand the charge-transfer and/or delocalization phenomena of these alloys. The experimental n3d values were found to be 3.2694, 4.7905, 7.7941, 7.9618, 8.500 for pure Ti, V, Fe, Co and Ni, respectively. The calculated 3d and 4s, 4p electron population values for Ti, V and Co in pure form have shown very little deviation from the appropriate values of Ti in Ti50Co50 and Co, V in PERMENDUR49. Also, the deviation for these values is greater for Fe, Ni, in KOVAR, Co in Ti50Co50, Fe in PERMENDUR49 with respect to the corresponding values of pure metals and the largest deviation for these values is observed for Co metal atoms in KOVAR alloy. We have also calculated the weighted average numbers of 3d and 4s, 4p electrons per one atom as well as the superposition of 3d and 4s, 4p electrons, as obtained from pure metal values. While the obtained superposition 3d electron numbers of present alloys exhibit a decreasing tendency as S3d(Ti50Co50) < S3d(PERMENDUR49) < S3d(KOVAR), the obtained weighted average 3d electron numbers of present alloys has opposite tendency (A3d(KOVAR) < A3d(PERMENDUR49) < A3d(Ti50Co50)). The analysis show that valance-electron population of elements in these alloys indicated differences with respect to the pure metal and each other. These differences can be related to type of alloy elements, concentration of alloy elements, charge transfer and/or delocalization phenomena between of individual metal atoms in alloys. Also, the obtained results show that there are alloying effect on valence-electron population due to charge transfer and/or delocalization phenomena.
AtıfScopus15WoS15OpenAlex16İncele