Akkuş, Tuba; Alım, Bünyamin; Yılmaz, Demet; Şahin, Yusuf

L X-ray differential cross-sections of uranium were calculated at several polar scattering angles (85°, 95°, 105°, 115°, 125°, and 135°) at 59.54-keV photon energy by using a Si(Li) detector. We observed that Ll and Lα X-rays were dependent on the polar scattering angle, whereas Lβ and Lγ X-rays were independent of the polar scattering angle. Therefore, the anisotropy parameters for Ll and Lα X-rays were obtained using the intensity ratios of Ll to Lγ X-rays and of Lα to Lγ X-rays to reduce some systematic errors.

AtıfScopus2·WoS2·OpenAlex2

İncele

Perişanoğlu, Ufuk; Alım, Bünyamin; Uğurlu, Mine; Demir, Lütfü

The effects of external magnetic field and exciting photon energies on the Kβ/Kα X-ray intensity ratios of various alloy compositions of Ti-Ni transition metal alloys have been investigated in this work using X-ray fluorescence spectroscopy. The spectrum of characteristic K-X-ray photons from pure Ti, pure Ni and TixNi1-x (x=0.30; 0.40; 0.50; 0.60; 0.70) alloys were detected with a high resolution Si (Li) solid-state detector. Firstly, Kβ/Kα X-ray intensity ratios of pure Ti, pure Ni and TixNi1-x alloys were measured following excitation by 59.54 keV γ-rays from a 200 mCi 241Am radioactive point source without any magnetic field and under 0.5 and 1 T external magnetic fields, separately. Later, the same measurements were repeated under the same experimental conditions for 22.69 keV X-rays from a 370 MBq109Cd radioactive point source. The results obtained for Kβ/Kα X-ray intensity ratios of pure Ti, pure Ni, Ti and Ni in various Ti-Ni alloys were evaluated in terms of both external magnetic field effect and exciting photon energy effect. When the results obtained for both exciting photon energies are evaluated in terms of changing of Kβ/Kα X-ray intensity ratios depending on the alloy composition, the tendency of these changes are observed to be similar. Also, Kβ/Kα X-ray intensity ratios for all samples examined have changed with increasing external magnetic field. Therefore, the results obtained have shown that Kβ/Kα X-ray intensity ratios of Ti and Ni in TixNi1−x alloys are connected with the external magnetic field. The present study makes it possible to perform reliable interpretation of experimental Kβ/Kα X-ray intensity ratios for Ti, Ni and TixNi1−x alloys and can also provide quantitative information about the changes of the Kβ/Kα X-ray intensity ratios of these metals with alloy composition.

AtıfScopus32·WoS31·OpenAlex32

İncele

Alim, Bünyamin; Han, Ibrahim; Demir, Lütfü

The effect of external magnetic field on the valence-electron structures of Fe and Ni in various Fe-Ni alloy compositions was investigated by using X-ray fluorescence spectroscopy. Kβ-to-Kα X-rayin-tensity ratios of Fe and Ni in Invar(Fe0.64Ni0.36), Permalloy(Fe0.20Ni0.80) and Fe N - i x 1x Firstly,(x=0, 0.40, 0.52, 0.55, 0.61, and 1) alloys were measured without any magnetic field and under 0.5 and 1 T external magnetic fields, separately. Later, the valence-electron structures of Fe and Ni in both pure form and alloys were obtained by comparison of measured X-ray intensity ratios with the results of multi-configurations Dirac-Fock (MCDF) calculations. The results obtained for valence-electron structures of Fe and Ni in various Fe-Ni alloys were evaluated in terms of magnetic field effect, delocalization and/or charge transfer phenomena. The results have shown that valence electron structure of Fe and Ni in Fe-Ni alloys are dependent on both external magnetic field and concentration of alloy elements.

AtıfScopus16·WoS14·OpenAlex17

İncele