The performance of Ag2S/X (X: Co and Ni) nanocrystals as counter electrodes in dye-sensitized solar cells

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Özet

In the present study, Silver sulfide (Ag2S)-based nanocrystals (NCs) were synthesized by employing a facile hot injection method. These NCs are utilized as counter electrodes on dye-sensitized solar cells (DSSCs), representing a smart approach that utilizes these NCs as catalysts instead of platinum (Pt) for the first time. The study provides a comparative analysis of the performance of Ag2S-based counter electrodes (CEs) in DSSCs technologies the traditionally compared Pt-based electrodes under identical conditions. The findings showed that the Ag2S-based DSSCs exhibited a power conversion efficiency (ƞ) that was approximately 5.2 % higher than that of the platinum-based DSSCs. Consequently, the results of this study demonstrate that Ag2S-based NCs possess the potential to function as novel counter electrode materials for low-cost, Pt-free solar cells. Moreover, the results of this study bear considerable implications for the development of cost-effective and sustainable solar energy solutions. The advent of Ag2S-based NCs signifies a significant milestone in the quest for sustainable and efficient energy solutions. This study also invites further exploration into other potential material combinations and synthesis methods that could enhance the properties and performance of DSSCs.

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https://rdlopen.rawdatalibrary.net/r/bayburt/11132Resmi atıflarda kullanılan kalıcı adres
DOI
https://doi.org/10.1016/j.poly.2025.117658Yayıncı resmi DOI adresi
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AlanDeğerDil
dc.contributor.authorOzel, Sultan Suleyman
dc.contributor.authorBulucu, Esen Dagasan
dc.contributor.authorSarilmaz, Adem
dc.contributor.authorOzel, Faruk
dc.date.accessioned2026-10-29T19:08:04.797436285Z
dc.date.available2026-10-29T19:08:04.797436285Z
dc.date.issued2025
dc.description.abstractIn the present study, Silver sulfide (Ag2S)-based nanocrystals (NCs) were synthesized by employing a facile hot injection method. These NCs are utilized as counter electrodes on dye-sensitized solar cells (DSSCs), representing a smart approach that utilizes these NCs as catalysts instead of platinum (Pt) for the first time. The study provides a comparative analysis of the performance of Ag2S-based counter electrodes (CEs) in DSSCs technologies the traditionally compared Pt-based electrodes under identical conditions. The findings showed that the Ag2S-based DSSCs exhibited a power conversion efficiency (ƞ) that was approximately 5.2 % higher than that of the platinum-based DSSCs. Consequently, the results of this study demonstrate that Ag2S-based NCs possess the potential to function as novel counter electrode materials for low-cost, Pt-free solar cells. Moreover, the results of this study bear considerable implications for the development of cost-effective and sustainable solar energy solutions. The advent of Ag2S-based NCs signifies a significant milestone in the quest for sustainable and efficient energy solutions. This study also invites further exploration into other potential material combinations and synthesis methods that could enhance the properties and performance of DSSCs.
dc.description.sponsorshipTürkiye Bilimsel ve Teknolojik Araştırma Kurumu, TUBITAK
dc.description.sponsorshipErciyes Üniversitesi, (FDK-2024-13705)
dc.description.sponsorshipErciyes Üniversitesi
dc.identifier.articlenumber117658
dc.identifier.doi10.1016/j.poly.2025.117658
dc.identifier.eissn1873-3719
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-105009241759
dc.identifier.urihttps://rdlopen.rawdatalibrary.net/r/bayburt/11132
dc.identifier.volume279
dc.identifier.wosWOS:001525861900001
dc.language.isoen
dc.publisherElsevier Ltd
dc.relation.ispartofPolyhedron
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAg<sub>2</sub>S/Co
dc.subjectAg<sub>2</sub>S/Ni
dc.subjectDye sensitized solar cells
dc.subjectPlatinum-free counter electrode
dc.subjectTransition elements
dc.subject.classificationChemistry, Inorganic & Nuclear
dc.subject.classificationCrystallography
dc.subject.classificationChemistry
dc.subject.otherConversion efficiency
dc.subject.otherCost effectiveness
dc.subject.otherElectrodes
dc.subject.otherEnergy efficiency
dc.subject.otherNanocrystals
dc.subject.otherNanostructured materials
dc.subject.otherPlatinum
dc.subject.otherPlatinum compounds
dc.subject.otherSilver compounds
dc.subject.otherSolar energy
dc.subject.otherSulfur compounds
dc.subject.otherAg2S/co
dc.subject.otherAg2S/ni
dc.subject.otherCo and Ni
dc.subject.otherCounter electrodes
dc.subject.otherDye- sensitized solar cells
dc.subject.otherEnergy solutions
dc.subject.otherPerformance
dc.subject.otherPlatinum-free counter electrode
dc.subject.otherSilver sulphide
dc.subject.otherTransition element
dc.subject.otherDye-sensitized solar cells
dc.titleThe performance of Ag2S/X (X: Co and Ni) nanocrystals as counter electrodes in dye-sensitized solar cells
dc.typeArticle
rdl.citation.openalex3
rdl.citation.scopus4
rdl.citation.wos3
rdl.oa.statusgreen
rdl.oa.urlhttps://doi.org/10.2139/ssrn.5260398
rdl.scopus.quartileQ3
rdl.sdgSDG07
rdl.source.indexSCOPUS
rdl.source.indexWOS
rdl.wos.indexScience Citation Index Expanded (SCI-EXPANDED)